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E1012

Epibromohydrin

Name: Epibromohydrin
Brand: ALDRICH

98%

Synonym(s):

1-Bromo-2,3-epoxypropane

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About This Item

Empirical Formula (Hill Notation):

C₃H₅BrO

CAS Number:

3132-64-7

Molecular Weight:

136.98

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24894378

EC Number:

221-525-3

Beilstein/REAXYS Number:

79786

MDL number:

MFCD00005130

Assay:

98%

Form:

liquid

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Quality Level

200

assay

98%

form

liquid

refractive index

n20/D 1.482 (lit.)

bp

134-136 °C (lit.)

mp

−40 °C (lit.)

density

1.601 g/mL at 25 °C (lit.)

SMILES string

BrCC1CO1

InChI

1S/C3H5BrO/c4-1-3-2-5-3/h3H,1-2H2

InChI key

GKIPXFAANLTWBM-UHFFFAOYSA-N

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Chemical Building Blocks

Organic Building Blocks

Application

Epibromohydrin can be used:

As an alkylating agent.
As a reactant in the multistep synthesis of analogs of febrifugine and P7C3.
To synthesize cyclic carbonates by coupling with CO₂ in the presence of bis(triphenylphosphine)immium(PPN)-manganese carbonyl catalyst.
For the synthesis of triazole-oxazolidinones possessing antibacterial activities.

pictograms

GHS02,GHS06,GHS08,GHS05

hcodes

H226,H301 + H311 + H331,H314,H317,H335,H351

signalword

Danger

pcodes

P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

138.2 °F - closed cup

flash_point_c

59 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Development of proneurogenic, neuroprotective small molecules.

MacMillan KS, et al.

Journal of the American Chemical Society, 133(5), 1428-1437 (2011)

Cyclin-dependent kinase 4 inhibitors as a treatment for cancer. Part 1: identification and optimisation of substituted 4, 6-bis anilino pyrimidines.

Beattie JF, et al.

Bioorganic & Medicinal Chemistry, 13(18), 2955-2960 (2003)

Synthesis of triazole-oxazolidinones via a one-pot reaction and evaluation of their antimicrobial activity.

Demaray JA, et al.

Bioorganic & Medicinal Chemistry Letters, 18(17), 4868-4871 (2008)

Imidazo [1, 2-a] pyridines: a potent and selective class of cyclin-dependent kinase inhibitors identified through structure-based hybridisation.

Anderson M, et al.

Bioorganic & Medicinal Chemistry, 13(18), 3021-3026 (2003)

Coupling reactions of CO2 with neat epoxides catalyzed by PPN salts to yield cyclic carbonates.

Sit WN, et al.

The Journal of Organic Chemistry, 70(21), 8583-8586 (2005)

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Global Trade Item Number

SKU	GTIN
E1012-100G-A	04061837018411
E1012-5G-A	04061833601310
E1012-500G-A	04061837018428

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