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Merck
CN

E45708

1-Ethylpiperidine

99%

Synonym(s):

N-Ethylpiperidine, NSC 2090

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About This Item

Empirical Formula (Hill Notation):
C7H15N
CAS Number:
766-09-6
Molecular Weight:
113.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24894564
EC Number:
212-161-6
Beilstein/REAXYS Number:
102643
MDL number:
MFCD00006507
Assay:
99%
Form:
liquid

Key Documents

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InChI key

HTLZVHNRZJPSMI-UHFFFAOYSA-N

InChI

1S/C7H15N/c1-2-8-6-4-3-5-7-8/h2-7H2,1H3

SMILES string

CCN1CCCCC1

assay

99%

form

liquid

refractive index

n20/D 1.444 (lit.)

bp

131 °C (lit.)

density

0.824 g/mL at 25 °C (lit.)

Quality Level

100

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Application

Reactant for:
Synthesis of multiprotected kanosamine
Selective acylation in peptide synthesis
Reagent for:
Stereoselective aldol condensation reactions for synthesis of β-lactam antibiotics
Diastereoselective synthesis of aldols
Crossed Claisen ester condensation

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

62.6 °F

flash_point_c

17 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
STBK3640
STBH1127
STBC4731V
S85313
S60670V

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Yoo Tanabe and Teruaki Mukaiyama
Chemistry Letters (Jpn), 11, 1813-1816 (1986)
Laurence Miesch, et al
Synthesis, 1, 161-167 (2011)
Amino-acids and peptides. XXIV. The use of esters of 1-hydroxypiperidine and of other NN-dialkylhydroxylamines in peptide synthesis and as selective acylating agents.
B O Handford et al.
Journal of the Chemical Society. Perkin transactions 1, Dec, 6814-6827 (1965-12-01)
Yoshimitsu Nagao, et al
Journal of the American Chemical Society, 20, 1418-1419 (1985)
Mankil Jung and Marvin J. Miller
Tetrahedron Letters, 26, 977-980 (1985)
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