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E50604

Ethyltriphenylphosphonium bromide

Name: Ethyltriphenylphosphonium bromide
Brand: ALDRICH

99%

Synonym(s):

TEP

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About This Item

Linear Formula:

[(C₆H₅)₃P⁺C₂H₅]Br^-

CAS Number:

1530-32-1

Molecular Weight:

371.25

UNSPSC Code:

12352002

NACRES:

NA.22

PubChem Substance ID:

24894599

EC Number:

216-223-3

Beilstein/REAXYS Number:

3599630

MDL number:

MFCD00011838

Assay:

99%

Form:

crystalline

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Properties

Quality Segment

200

assay

99%

form

crystalline

reaction suitability

core: phosphonium, reaction type: C-C Bond Formation

mp

203-205 °C (lit.)

SMILES string

[Br-].CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C20H20P.BrH/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h3-17H,2H2,1H3;1H/q+1;/p-1

InChI key

JHYNXXDQQHTCHJ-UHFFFAOYSA-M

Description

Application

Reactant for synthesis of:

D-amino acids from L-cysteine-derived thiazolidines
Leiodolide A via aldol reactions and Horner-Wadsworth-Emmons olefination
Cycloalkanoindolines via diastereoselective intramolecular inimo-ene reactions
WXYZA′ domain of maitotoxin using the coupling of key building blocks

Reactant for:

Solid-state metathesis polycondensation to form alkyl-dipropenylthiophene monomers
Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization / lactonization cyclization reactions for synthesis of an ABC ring system

pictograms

GHS06,GHS05

signalword

Danger

hcodes

H301,H318,H412

pcodes

P264 - P273 - P280 - P301 + P310 - P305 + P351 + P338 - P405

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2

flash_point_f

401.0 °F

flash_point_c

205 °C

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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