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About This Item
Empirical Formula (Hill Notation):
Rh
CAS Number:
Molecular Weight:
102.91
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141738
MDL number:
InChI
1S/Rh
SMILES string
[Rh]
InChI key
MHOVAHRLVXNVSD-UHFFFAOYSA-N
assay
99.90%
form
wire
manufacturer/tradename
Goodfellow 274-990-45
resistivity
4.33 μΩ-cm, 20°C
L × diam.
0.1 m × 0.25 mm
bp
3727 °C (lit.)
mp
1966 °C (lit.)
density
12.41 g/cm3 (lit.)
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General description
For updated SDS information please visit www.goodfellow.com.
Legal Information
Product of Goodfellow
Storage Class
13 - Non Combustible Solids
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms
Albert Padwa
Chemical Society reviews, 38(11), 3072-3081 (2009-10-23)
In this tutorial review, the rhodium(II)-catalyzed domino reactions of alpha-diazo carbonyl compounds are summarized. The article will emphasize some of the more recent synthetic applications of the rhodium carbenoid cyclization/cycloaddition domino cascade for alkaloid synthesis. The many structurally diverse and
Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.
Denise A Colby et al.
Chemical reviews, 110(2), 624-655 (2009-05-15)
Jan Meine Ernsting et al.
Magnetic resonance in chemistry : MRC, 42(9), 721-736 (2004-08-13)
Rhodium is used for a number of large processes that rely on homogeneous rhodium-catalyzed reactions, for instance rhodium-catalyzed hydroformylation of alkenes, carbonylation of methanol to acetic acid and hydrodesulfurization of thiophene derivatives (in crude oil). Many laboratory applications in organometallic
Feng Shi et al.
Topics in current chemistry, 292, 123-164 (2010-01-01)
The catalytic activation of a C-H bond is a fundamentally important organic transformation. There are now numerous reports of palladium-mediated C-H activation by the through-space interaction of a palladium center with a neighboring C-H bond. This type of C-H activation
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