Skip to Content
Merck
CN

H10401

Hexamethyleneimine

99%

Synonym(s):

1-Azacycloheptane, Azepane, HMI, Perhydroazepine, Hexahydro-1H-azepine, Homopiperidine

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Empirical Formula (Hill Notation):
C6H13N
CAS Number:
111-49-9
Molecular Weight:
99.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24895424
EC Number:
203-875-9
Beilstein/REAXYS Number:
1084
MDL number:
MFCD00006934
Assay:
99%
Form:
liquid

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI

1S/C6H13N/c1-2-4-6-7-5-3-1/h7H,1-6H2

InChI key

ZSIQJIWKELUFRJ-UHFFFAOYSA-N

SMILES string

C1CCCNCC1

vapor pressure

7.4 mmHg ( 21.1 °C)

assay

99%

form

liquid

refractive index

n20/D 1.466 (lit.)

bp

138 °C/749 mmHg (lit.)

density

0.88 g/mL at 25 °C (lit.)

Quality Level

100

Related Categories

Application

Hexamethyleneimine (HMI) can be used in the preparation of:
  • zeolitic catalysts such as MCM-22 and MCM-49
  • SAPO-35, a molecular sieve
  • various microporous aluminosilicates and titanosilicates
  • organic-inorganic hybrid pervoskite


It can also been used in the total synthesis of various natural products and bioactive molecules such as (−)-balanol, indole estrogens, derivatives of daunorubicin and (+)-cetiedil.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1C - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

64.4 °F - closed cup

flash_point_c

18 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCZ9491
MKCX8975
MKCX8974
MKCX7840
MKCV3437

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Design, synthesis, and preclinical characterization of novel, highly selective indole estrogens.
Miller CP, et al.
Journal of Medicinal Chemistry, 44(11), 1654-1657 (2001)
Zeolite MCM-49: a three-dimensional MCM-22 analogue synthesized by in situ crystallization.
Lawton SL, et al.
The Journal of Physical Chemistry, 100(9), 3788-3798 (1996)
Synthesis of zeolite MCM-22 under rotating and static conditions. Microporous and mesoporous materials.
Guray I, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 31(3), 241-251 (1999)
Synthesis of SAPO-35 in non-aqueous gels.
Venkatathri N, et al.
J. Chem. Soc., Faraday Trans., 93(18), 3411-3415 (1997)
Direct Dual?Template Synthesis of MWW Zeolite Monolayers.
Margarit VJ, et al.
Angewandte Chemie (International Edition in English), 127(46), 13928-13932 (2015)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service