CN
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L512028

Sigma-Aldrich

iso-Propyl stannatrane

AldrichCPR

Synonym(s):
5-(iso-Propyl)-1-aza-5-stannabicyclo[3.3.3]undecane
Empirical Formula (Hill Notation):
C12H25NSn
Molecular Weight:
302.04
MDL number:
PubChem Substance ID:

Quality Level

SMILES string

CC(C)[Sn]1(CCC2)CCCN2CCC1

InChI

1S/C9H18N.C3H7.Sn/c1-4-7-10(8-5-2)9-6-3;1-3-2;/h1-9H2;3H,1-2H3;

InChI key

SJHQOVXNCVULMJ-UHFFFAOYSA-N

Application

Secondary stannatranes are an innovative source of a secondary nucleophile for Pd-catalyzed cross-coupling and have been reported to provide more convenience over alternatives, e.g. boronates, Grignards, etc.

Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides.

Other Notes

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

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