M46209
1,3,3-Trimethyl-2-methyleneindoline
97%
Synonym(s):
2-Methylene-1,3,3-trimethylindoline, Fischer base, NSC 66176
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About This Item
Empirical Formula (Hill Notation):
C12H15N
CAS Number:
Molecular Weight:
173.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-235-1
Beilstein/REAXYS Number:
131162
MDL number:
Assay:
97%
Form:
liquid
InChI key
ZTUKGBOUHWYFGC-UHFFFAOYSA-N
InChI
1S/C12H15N/c1-9-12(2,3)10-7-5-6-8-11(10)13(9)4/h5-8H,1H2,2-4H3
SMILES string
CN1C(=C)C(C)(C)c2ccccc12
assay
97%
form
liquid
Quality Level
bp
248 °C (lit.)
density
0.979 g/mL at 25 °C (lit.)
Related Categories
Application
Reactant for:
- Cycloaddition reactions
- Preparation of red photochromic dyes
- Synthesis of photochromic homopolymers via ring-opening metathesis polymerization
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1
Storage Class
10 - Combustible liquids
wgk
WGK 2
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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York, M.; Evans, R., A.
Tetrahedron Letters, 51, 2195-2195 (2010)
Ishmetova, R., I.; et al.
Heterocycles, 83, 1363-1363 (2011)
Keum, S., et al.
Dyes and Pigments, 86, 74-74 (2010)
Maryam Raeesi et al.
Journal of colloid and interface science, 578, 379-389 (2020-06-15)
One of the biggest challenges in the field of photoresponsive spirooxazines is their fast reverse isomerization. Polar phase change materials beside spirooxazines not only stabilize their colored-form, but also induce thermo-regulating properties to the whole system. Moreover, encapsulation is a
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