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About This Item
Empirical Formula (Hill Notation):
C5H11NO
CAS Number:
Molecular Weight:
101.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-640-0
Beilstein/REAXYS Number:
102719
MDL number:
Assay:
99%
Bp:
115-116 °C/750 mmHg (lit.)
Vapor pressure:
18 mmHg ( 20 °C)
vapor density
>1 (vs air)
Quality Level
vapor pressure
18 mmHg ( 20 °C)
product line
ReagentPlus®
assay
99%
form
liquid
dilution
(for general lab use)
refractive index
n20/D 1.435 (lit.)
bp
115-116 °C/750 mmHg (lit.)
mp
−66 °C (lit.)
density
0.92 g/mL at 25 °C (lit.)
SMILES string
CN1CCOCC1
InChI
1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3
InChI key
SJRJJKPEHAURKC-UHFFFAOYSA-N
General description
4-methylmorpholine, also known as N-Methylmorpholine, is a cyclic tertiary amine and is commonly used as a highly valuable solvent and a fine chemical for cellulose.
Application
4-Methylmorpholine can be used to synthesize N-butyl-N-methylmorpholinium bromide by reacting with bromobutane.
4-methylmorpholine is used:
- in the synthesis of N-methylmorpholine-N-oxide (NMMO)
- as an effective and inexpensive additive for highly enantioselective arylation of aryl aldehydes catalyzed by the (S)-H8-BINOL-Ti(Oi-Pr)2 complex
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
53.6 °F - closed cup - DIN 51755 Part 1
flash_point_c
12 °C - closed cup - DIN 51755 Part 1
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Size-controlled electrochemical synthesis of palladium nanoparticles using morpholinium ionic liquid.
Cha J H, et al.
Korean Journal of Chemical Engineering, 24(6), 1089-1094 (2007)
Benedetta Del Secco et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 18(9), 2142-2149 (2019-04-24)
Silica nanoparticles (NPs) are versatile nanomaterials, which are safe with respect to biomedical applications, and therefore are highly investigated. The advantages of NPs include their ease of preparation, inexpensive starting materials and the possibility of functionalization or loading with various
L Hansén et al.
Scandinavian journal of work, environment & health, 12(1), 66-69 (1986-02-01)
The N-methylmorpholine levels in workroom air in a polyurethane foam factory were determined by two methods in which midget impinger flasks were used for sampling. The analyses were performed by gas chromatography and isotachophoresis. The values obtained by the gas
Global Trade Item Number
| SKU | GTIN |
|---|---|
| M56557-100ML | 04061834060185 |
| M56557-500ML | 04061834060192 |


