M9653
Methoxyacetyl chloride
97%
Synonym(s):
2-methoxyacetyl chloride, Methoxyacetic acid chloride
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About This Item
Linear Formula:
CH3OCH2COCl
CAS Number:
Molecular Weight:
108.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
254-169-2
Beilstein/REAXYS Number:
1740244
MDL number:
Assay:
97%
Form:
liquid
Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.419 (lit.)
bp
112-113 °C (lit.)
density
1.187 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
COCC(Cl)=O
InChI
1S/C3H5ClO2/c1-6-2-3(4)5/h2H2,1H3
InChI key
JJKWHOSQTYYFAE-UHFFFAOYSA-N
Application
Methoxyacetyl chloride can be used for methoxyacetylation of:
It can also be used for the synthesis of β-lactams by reacting with imines. and in the post-synthetic modification of the metal-organic framework (MOF), MIL-101, to synthesize a catalyst for cycloaddition reaction of CO2 with propylene oxide.
- Bilocularin A to synthesize 8-Methoxyacetoxybilocularin A.
- Substituted and unsubstituted benzamides to synthesize N-(2-methoxyacetyl)-benzamides.
It can also be used for the synthesis of β-lactams by reacting with imines. and in the post-synthetic modification of the metal-organic framework (MOF), MIL-101, to synthesize a catalyst for cycloaddition reaction of CO2 with propylene oxide.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
82.4 °F
flash_point_c
28 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Synthesis of Quinolinone Alkaloids via Aryne Insertions into Unsymmetric Imides in Flow.
Schwan J, et al.
Organic Letters, 20(23), 7661?7664-7661?7664 (2018)
Bioactive dihydro-?-agarofuran sesquiterpenoids from the Australian rainforest plant Maytenus bilocularis.
Wibowo M, et al.
Journal of Natural Products, 79(5), 1445-1453 (2016)
Functionalized MIL-101 with imidazolium-based ionic liquids for the cycloaddition of CO2 and epoxides under mild condition.
Liu D, et al.
Applied Surface Science, 428(45), 218-225 (2018)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| M9653-10G | 04061834064473 |
| M9653-1G | 04061836690526 |