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N32601

Sigma-Aldrich

Norcamphor

98%

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Synonym(s):
2-Norbornanone, Bicyclo[2.2.1]heptan-2-one
Empirical Formula (Hill Notation):
C7H10O
CAS Number:
Molecular Weight:
110.15
Beilstein:
1209657
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

crystals

bp

168-172 °C (lit.)

mp

93-96 °C (lit.)

SMILES string

O=C1C[C@@H]2CC[C@H]1C2

InChI

1S/C7H10O/c8-7-4-5-1-2-6(7)3-5/h5-6H,1-4H2/t5-,6+/m1/s1

InChI key

KPMKEVXVVHNIEY-RITPCOANSA-N

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Related Categories

Pictograms

Flame

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

91.4 °F - closed cup

Flash Point(C)

33 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. Is Product N32601, Norcamphor, a single enantiomer or a mixture?

    This product consists of equal parts of both enantiomers and is therefore racemic.

  6. In what solvent is Product N32601, Norcamphor, soluble?

    According to our quality control testing, norcamphor is expected to be soluble in 95% ethanol at about 10% (w/v), or 100 mg/mL.

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Megan C Thielges et al.
The journal of physical chemistry. A, 115(34), 9714-9723 (2011-06-09)
Progress in the field of 2D IR vibrational spectroscopy has been bolstered by the production of intense mid-IR laser pulses. As higher-energy pulses are employed, a concomitant increase occurs in the likelihood of fifth-order contributions to the 2D IR spectra.
P J Loida et al.
The Journal of biological chemistry, 270(10), 5326-5330 (1995-03-10)
The stereoselectivity of cytochrome P450cam hydroxylation has been investigated with the enantiomerically pure substrate analog norcamphor. (1R)- and (1S)-norcamphor (> 92 enantiomeric excess) were characterized in the hydroxylation reaction with cytochrome P450cam with respect to the product profile, steady state
Marko D Mihovilovic et al.
ChemSusChem, 1(1-2), 143-148 (2008-07-09)
Recombinant Escherichia coli cells expressing monooxygenases of different bacterial origin were evaluated in microbial Baeyer-Villiger oxidations of racemic fused ketones. During the enzymatic oxidation process, both the "normal" lactone generated by migration of the more-substituted carbon atom and/or the "abnormal"
Christiane Jung et al.
European journal of biochemistry, 269(12), 2989-2996 (2002-06-20)
The high-pressure stopped-flow technique is applied to study the CO binding in cytochrome P450cam (P450cam) bound with homologous substrates (1R-camphor, camphane, norcamphor and norbornane) and in the substrate-free protein. The activation volume DeltaV # of the CO on-rate is positive
Sergio Abbate et al.
The journal of physical chemistry. A, 113(42), 11390-11405 (2009-09-30)
The absorption spectra and vibrational circular dichroism (VCD) spectra in the mid-IR range 1600-950 cm(-1) of 10 camphor-related compounds have been recorded and compared to DFT calculated spectra at the B3PW91/TZ2P level and have been examined together with the corresponding

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