P27127
Phenylmercuric acetate
97%
Synonym(s):
Phenylmercury acetate, Mercury phenyl acetate
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About This Item
Linear Formula:
C6H5HgOCOCH3
CAS Number:
Molecular Weight:
336.74
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-532-5
Beilstein/REAXYS Number:
3662930
MDL number:
Quality Segment
assay
97%
form
powder
mp
148-151 °C (lit.)
SMILES string
CC(=O)O[Hg]c1ccccc1
InChI
1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1
InChI key
XEBWQGVWTUSTLN-UHFFFAOYSA-M
Application
Phenylmercuric acetate (PMA) can react with a palladium salt such as palladium acetate to form an arylpalladium salt in situ, which then reacts with primary or secondary allylic alcohols to produce 3-aryl aldehydes. It can also be used in the multi-step synthesis of 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl thiol via Floyd′s pathway.
Disclaimer
For U.S. Customers: Contains mercury; Do not place in trash - dispose according to local, state, or federal laws.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1
target_organs
Kidney,Central nervous system
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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