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About This Item
Empirical Formula (Hill Notation):
C3H6O3
CAS Number:
Molecular Weight:
90.08
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-812-5
Beilstein/REAXYS Number:
102769
MDL number:
Assay:
≥99%
InChI
1S/C3H6O3/c1-4-2-6-3-5-1/h1-3H2
InChI key
BGJSXRVXTHVRSN-UHFFFAOYSA-N
SMILES string
C1OCOCO1
assay
≥99%
autoignition temp.
777 °F
expl. lim.
29 %
Quality Level
mp
59-62 °C (lit.)
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Application
1,3,5-Trioxane is widely used as a source of anhydrous formaldehyde.
It can be used to synthesize:
It can be used to synthesize:
- Polyoxymethylene and hyperbranched polyesters.
- Calixarenes such as calix[4]resorcinarene, calix[6]resorcinarene and para-tert-butylcalix[8] and [9]arene.
- Various natural products including (−)-motuporin, (+)-sundiversifolide, (+)-lyconadin A and (−)-lyconadin B.
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Repr. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 1
flash_point_f
113.0 °F - closed cup
flash_point_c
45 °C - closed cup
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
危险化学品
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The Lyconadins: enantioselective total syntheses of (+)-lyconadin A and (−)-lyconadin B.
Beshore DC and Smith AB.
Journal of the American Chemical Society, 130(41), 13778-13789 (2008)
Single step synthesis of peripherally ?clickable? hyperbranched polyethers.
Saha A and Ramakrishnan S.
Macromolecules, 42(14), 4956-4959 (2009)
Hexahydro?1, 3, 5?tripropionyl?s?triazine.
Teeters WO and Gradsten MA.
Organic Syntheses, 51-51 (2003)
Cationic Copolymerization of 1, 3, 5-Trioxane with 1, 3-Dioxepane: A Comprehensive Approach to the Polyacetal Process.
Sharavanan K, et al.
Macromolecules, 42(22), 8702-8710 (2009)
Enantioselective synthesis of the protein phosphatase inhibitor (−)-motuporin.
Hu T and Panek JS.
Journal of the American Chemical Society, 124(38), 11368-11378 (2002)
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