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Merck
CN

V1902

Vinyl bromide

98%

Synonym(s):

Bromoethylene

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About This Item

Linear Formula:
CH2=CHBr
CAS Number:
Molecular Weight:
106.95
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
209-800-6
Beilstein/REAXYS Number:
1361370
MDL number:
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vapor density

3.8 (15 °C, vs air)

Quality Level

vapor pressure

1551 mmHg ( 37.8 °C)

assay

98%

autoignition temp.

986 °F

contains

200 ppm monomethyl ether hydroquinone as inhibitor

expl. lim.

15 %

bp

16 °C/750 mmHg (lit.)

mp

−139 °C (lit.)

density

1.517 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

BrC=C

InChI

1S/C2H3Br/c1-2-3/h2H,1H2

InChI key

INLLPKCGLOXCIV-UHFFFAOYSA-N

Application

  • FTIR and Raman Spectroscopy Study of Soot Deposits: Investigates soot formation during the infrared multiphoton dissociation of vinyl bromide, suggesting potential applications in materials science regarding soot characteristics (Samoudi et al., 2022).
  • Nickel-Catalyzed Reductive Cross-Coupling: Describes a method for coupling vinyl bromides with unactivated alkyl halides, highlighting its utility in synthetic organic chemistry for creating complex molecules (Gong et al., 2017).
  • Silver-Promoted Synthesis of Vinyl Sulfones: This study explores the reactivity of vinyl bromides with sulfonyl hydrazides under aqueous conditions, applicable to pharmaceutical synthesis due to the biorelevance of sulfones (Zhang et al., 2020).
  • Visible Light on Vinyl Halides: Examines the photocatalytic properties of vinyl bromides, which could influence the development of green chemistry applications (Pagire et al., 2020).
  • Palladium Catalyzed Cross-Coupling of Diboronates: Focuses on the reactions of vinyl bromides with diboronates, offering insights into new methodologies for constructing biologically active compounds (Li et al., 2014).

Other Notes

V1902-100 g, V1902-900 g, and 1902-2.2 kg includes installed 316SS needle valve.
Stainless steel hose adapter Z146838 or stainless steel body mini gas regulator Z513547 is recommended.


signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 1B - Flam. Gas 1A - Press. Gas Liquefied gas

Storage Class

2A - Gases

wgk

WGK 3

flash_point_f

55.4 °F

flash_point_c

13 °C

ppe

Eyeshields, Faceshields, Gloves

Regulatory Information

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James A Marshall et al.
Organic letters, 6(3), 445-448 (2004-01-30)
[reaction: see text] Additions of vinylic zinc bromide reagents to alpha-chiral aldehydes (R(1) = CH(2)OTBS, R(2) = Me; R(1) = Me, R(2) = OTBS) in the presence of lithiated (+)- or (-)-N-methylephedrine proceed with predominant reagent control to afford anti
Qiwu Zhao et al.
The Journal of organic chemistry, 74(1), 459-462 (2008-11-27)
With CuI as the catalyst and K(3)PO(4) x 3 H(2)O as the base, highly efficient intramolecular S-vinylation of thiols with vinyl chlorides or bromides was successfully implemented without the help of an additional ligand. Moreover, the competition experiments revealed that
Mina Lee et al.
The Journal of chemical physics, 123(17), 174310-174310 (2005-12-27)
The vibrational spectrum of the vinyl bromide cation in the first excited electronic state A 2A' was obtained by one-photon mass-analyzed threshold ionization (MATI) spectroscopy. The use of an improved vacuum-ultraviolet radiation source based on four-wave sum frequency mixing in



Global Trade Item Number

SKUGTIN
V1902-100G04061833614952
V1902-2.2KG04061833614969
V1902-900G04061837480706