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Safety Information

W400201

Sigma-Aldrich

Methyl methacrylate

99%, stabilized

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Synonym(s):
Methyl 2-methylacrylate, Methyl 2-methylprop-2-enoate, Methyl 2-methylpropenoate
Linear Formula:
CH2=C(CH3)COOCH3
CAS Number:
80-62-6
Molecular Weight:
100.12
FEMA Number:
4002
Beilstein:
605459
EC Number:
201-297-1
MDL number:
MFCD00008587
PubChem Substance ID:
24901967
Flavis number:
9.647
NACRES:
NA.21

biological source

synthetic

Quality Level

400

vapor density

3.5 (vs air)

vapor pressure

29 mmHg ( 20 °C)

Assay

99%

autoignition temp.

815 °F

contains

hydroquinone monomethyl ether as stabilizer

expl. lim.

12.5 %

refractive index

n20/D 1.414 (lit.)

bp

100 °C (lit.)

mp

−48 °C (lit.)

density

0.936 g/mL at 25 °C (lit.)

application(s)

flavors and fragrances

Documentation

see Safety & Documentation for available documents

food allergen

no known allergens

Organoleptic

fruity

SMILES string

COC(=O)C(C)=C

InChI

1S/C5H8O2/c1-4(2)5(6)7-3/h1H2,2-3H3

InChI key

VVQNEPGJFQJSBK-UHFFFAOYSA-N

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General description

Methyl methacrylate is mainly used in the preparation of polymethyl methacrylate, a bone cement material.

Disclaimer

For R&D or non-EU Food use. Not for retail sale.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H225 - H315 - H317 - H335

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

50.0 °F - closed cup

Flash Point(C)

10 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

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Occupational Hazards in the Health Professions, 142-142 (1989)
Michael M Bornstein et al.
Journal of endodontics, 41(6), 804-811 (2015-04-13)
The aim of this study was to evaluate the concordance of 2- and 3-dimensional radiography and histopathology in the diagnosis of periapical lesions. Patients were consecutively enrolled in this study provided that preoperative periapical radiography (PR) and cone-beam computed tomographic
Alina Badina et al.
Clinical orthopaedics and related research, 471(11), 3701-3705 (2013-05-16)
Acetabular fractures are rare in children and can be complicated by premature fusion of the triradiate cartilage resulting in secondary acetabular dysplasia. Early recognition and treatment of a physeal bar in this location can be difficult. The purpose of this
Terumasa Kato et al.
The Journal of organic chemistry, 78(17), 8739-8747 (2013-08-15)
We and others have previously reported the intermolecular umpolung reactions of Michael acceptors catalyzed by an N-heterocyclic carbene (NHC). The representative tail-to-tail dimerization of methyl methacrylate (MMA) has now been intensively investigated, leading to the following conclusions: (1) The catalysis
Fabrice Audouin et al.
Biomacromolecules, 13(11), 3787-3794 (2012-10-20)
Amino-functional macroporous monoliths from polymerized high internal phase emulsion (polyHIPE) were surface modified with initiators for atom transfer radical polymerization (ATRP). The ATRP initiator groups on the polyHIPE surface were successfully used to initiate activator regeneration by electron transfer (ARGET)
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