1.12393
Vanadium(III) chloride
99+
Sustainability features
Synonym(s):
Vanadium(III) chloride, Vanadium trichloride
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About This Item
Empirical Formula (Hill Notation):
Cl3V
CAS Number:
Molecular Weight:
157.30
UNSPSC Code:
12352302
EC Index Number:
231-744-6
NACRES:
NA.22
MDL number:
Form:
solid
Quality Segment
form
solid
potency
350 mg/kg LD50, oral (Rat)
reaction suitability
reagent type: inorganic catalyst
sustainability
Sustainability features
density
3.0 g/cm3 at 20 °C
bulk density
1000 kg/m3
storage temp.
no temp limit
SMILES string
[V](Cl)(Cl)Cl
InChI
1S/3ClH.V/h3*1H;/q;;;+3/p-3
InChI key
HQYCOEXWFMFWLR-UHFFFAOYSA-K
General description
This productaligns with the Green Chemistry Principle of Catalysis. Click here for more information.
Application
Vanadium(III) chloride (VCl3) can be used as a catalyst to synthesize:
VCl3 can also be used as a reducing agent to determine nitrates and nitrites in water samples.
- Dihydropyrimidinone derivatives via a three-component Biginelli condensation reaction between aldehyde, β-keto ester, and urea (thiourea).
- Coumarin derivatives via Pechmann condensation reaction of various phenols and β-keto esters.
- β-amino alcohols by deprotection of epoxides with aromatic amines.
- Diol derivatives by chemoselective cleavage of acetonides in methanol.
VCl3 can also be used as a reducing agent to determine nitrates and nitrites in water samples.
Analysis Note
Assay (complexometric): ≥ 99.0 %
Identity (ICP-OES): passes test
Identity (ICP-OES): passes test
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Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
supp_hazards
Storage Class
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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