1.13364
Tetrahydrofuran-d8
deuteration degree min 99.5% for NMR spectroscopy MagniSolv™
Synonym(s):
THF deuterated, Deuterated tetrahydrofuran, Octadeuterotetrahydrofuran
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About This Item
Product Name
Tetrahydrofuran-d8, deuteration degree min 99.5% for NMR spectroscopy MagniSolv™
InChI
1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2
SMILES string
[2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]
InChI key
WYURNTSHIVDZCO-SVYQBANQSA-N
form
liquid
autoignition temp.
215 °C
potency
1650 mg/kg LD50, oral (Rat)
technique(s)
NMR: suitable
impurities
≤0.030% Water (H<SUB>2</SUB>O) (NMR)
≤0.050% Water (H<SUB>2</SUB>O) (Karl Fischer)
refractive index
n20/D 1.403 (lit.)
bp
65-66 °C (lit.)
mp
−106 °C (lit.)
transition temp
flash point -17.5 °C
density
0.985 g/mL at 25 °C (lit.)
mass shift
M+8
storage temp.
2-8°C
Quality Level
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Analysis Note
Water (NMR, H₂O): ≤ 0.030 %
Performance test (NMR-spectrum): passes test
Water (K. Fischer, H₂O + D₂O): ≤ 0.050 %
Application
- Experimental and Theoretical Study of CO2 Insertion into Ruthenium Hydride Complexes.: This research provides insights into the mechanistic pathways for CO2 reactivity with ruthenium hydride complexes, potentially relevant for catalytic applications including transformations involving Tetrahydrofuran-d₈ (Ramakrishnan et al., 2016).
- Syntheses, structures, and NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds.: Details the synthesis and structural characterization of trimethyltin compounds, useful for understanding the coordination chemistry that may involve Tetrahydrofuran-d₈ as a solvent or structural analogue (Lichtscheidl et al., 2015).
- NMR studies of coupled low- and high-barrier hydrogen bonds in pyridoxal-5′-phosphate model systems in polar solution.: Discusses the application of NMR spectroscopy in studying hydrogen bonding interactions, where Tetrahydrofuran-d₈ could be utilized as a deuterated solvent for enhanced spectral clarity (Sharif et al., 2007).
- Stable hydrocarbon diradical, an analogue of trimethylenemethane.: Investigates stable hydrocarbon diradicals, where Tetrahydrofuran-d₈ may be used as part of the experimental setup to stabilize reactive intermediates or as a solvent to study radical stability (Rajca et al., 2005).
General description
Other Notes
Legal Information
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Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Certificates of Analysis (COA)
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