MX1123
1-Methylimidazole
Synonym(s):
1-Methylimidazole, N-Methylimidazole, dna
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Linear Formula:
CH3-NCH=NCH=CH-
CAS Number:
UNSPSC Code:
12352100
EC Index Number:
210-484-7
MDL number:
Form:
liquid
vapor pressure
0.4 hPa ( 20 °C)
Quality Level
form
liquid
pH
9.5-10.5 (20 °C, 50 g/L in H2O)
bp
198 °C/1013 hPa
mp
-2 °C
transition temp
flash point 92 °C
shipped in
ambient
storage temp.
room temp
SMILES string
[n]1(cncc1)C
InChI
1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3
InChI key
MCTWTZJPVLRJOU-UHFFFAOYSA-N
Application
1-Methylimidazole can be used as an organocatalyst to synthesize:
It can also be used as:
- 4-amino-3,5-dicyano-6-arylphthalates via one-pot, a three-component reaction between arylidenemalononitriles, dialkyl acetylenedicarboxylates, and malononitrile.
- Aromatic and aliphatic carbamates from hydroxamic acids via the Lossen rearrangement.
- Tetrahydrobenzo[b]pyrans via three-component cyclocondensation reaction between aromatic aldehydes, malononitrile, and dimedone.
It can also be used as:
- A co-catalyst in copper-catalyzed, greener oxidation of alcohols to carbonyl compounds under aerobic conditions.
- A solvent/complexing agent in the preparation of CuInS2 n-type semiconductive particles.
- A co-additive in the synthesis of acid-sensitive epoxides by methyltrioxorhenium-catalyzed epoxidation of alkenes with H2O2.
Analysis Note
Assay (GC)99.0% minDensity at 20°C1.03-1.04g/mLFormClear, liquidWater (H2O)150ppm max
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
flash_point_f
197.6 °F - closed cup
flash_point_c
92 °C - closed cup
Regulatory Information
新产品
This item has
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Synthesis of n-type CuInS2 particles using N-methylimidazole, characterization and growth mechanism
Courtel FM, et al.
Chemistry of Materials, 22(12), 3752-3761 (2010)
1-Methylimidazole-catalyzed regioselective synthesis of highly substituted benzenes
Adib Mehdi, et al.
Synlett, 2007(16), 2497-2500 (2007)
Shigekazu Yamazaki
Organic & biomolecular chemistry, 8(10), 2377-2385 (2010-05-08)
An effective method for suppression of ring opening and rearrangement of acid-sensitive epoxides during methyltrioxorhenium(MTO)-catalyzed epoxidation of alkenes with H(2)O(2) by using 1-methylimidazole as a co-additive has been found. The combined use of 3-methylpyrazole and 1-methylimidazole as the additives has
Global Trade Item Number
| SKU | GTIN |
|---|---|
| MX1123-P4000 | 04061839429987 |