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Merck
CN

07-3750

Diiodomethane

SAJ first grade, ≥98.0%

Synonym(s):

Methylene iodide

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About This Item

Empirical Formula (Hill Notation):
CH2I2
CAS Number:
Molecular Weight:
267.84
EC Number:
200-841-5
UNSPSC Code:
12352101
PubChem Substance ID:
Beilstein/REAXYS Number:
1696892
MDL number:
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InChI key

NZZFYRREKKOMAT-UHFFFAOYSA-N

InChI

1S/CH2I2/c2-1-3/h1H2

SMILES string

ICI

grade

SAJ first grade

vapor density

9.25 (vs air)

assay

≥98.0%

form

liquid

availability

available only in Japan

bp

67-69 °C/11 mmHg (lit.)

mp

5-8 °C (lit.)

density

3.325 g/mL at 25 °C (lit.)

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pictograms

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signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

Regulatory Information

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Qingyu Kong et al.
The journal of physical chemistry. A, 109(45), 10451-10458 (2006-07-13)
Various molecular species are known to form during the photoreaction of C2H4I2 in the gas phase and in solution. We have studied all species involved in this reaction by ab initio and density functional theory (DFT) calculations: Geometries, energies, and
Eun Chul Cho et al.
Langmuir : the ACS journal of surfaces and colloids, 24(18), 9974-9978 (2008-08-21)
This study presents a method to measure the contact angles of oils on a substrate in water. Diiodomethane and perfluorodecalin were used as model oils. Self-assembled monolayers (SAMs) were prepared by adjusting the mole ratio of CH 3- and OH-terminated
H Ihee et al.
Science (New York, N.Y.), 309(5738), 1223-1227 (2005-07-16)
We report direct structural evidence of the bridged radical (CH2ICH2.) in a polar solution, obtained using time-resolved liquid-phase x-ray diffraction. This transient intermediate has long been hypothesized to explain stereo-chemical control in many association and/or dissociation reactions involving haloalkanes. Ultrashort
Elodie Velzenberger et al.
Colloids and surfaces. B, Biointerfaces, 68(2), 238-244 (2008-12-26)
Wettability of biomaterials surfaces and protein-coated substrates is generally characterized with the sessile drop technique using polar and apolar liquids. This procedure is often performed in air, which does not reflect the physiological conditions. In this study, liquid/liquid contact angle
Razak Kadir et al.
Environmental science & technology, 43(13), 5113-5116 (2009-08-14)
An optical sensor sensitive to BTX has been developed by spin coating a thin film of polyacrylate resin onto a tin- diffused glass optical waveguide. A pair of prism coupler was employed for optical coupling matched with diiodomethane (CH2l2). The

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