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Merck
CN

30-4640

Trimethyl phosphate

SAJ first grade, ≥95.0%

Synonym(s):

TMP, TMPA, TMPO

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About This Item

Linear Formula:
(CH3O)3PO
CAS Number:
Molecular Weight:
140.07
PubChem Substance ID:
UNSPSC Code:
12352108
Beilstein/REAXYS Number:
1071731
MDL number:
Assay:
≥95.0%
Grade:
SAJ first grade
Form:
liquid
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grade

SAJ first grade

assay

≥95.0%

form

liquid

availability

available only in Japan

refractive index

n20/D 1.395 (lit.)

bp

197 °C (lit.)

mp

−46 °C (lit.)

density

1.197 g/mL at 25 °C (lit.)

storage temp.

15-25°C

SMILES string

COP(=O)(OC)OC

InChI

1S/C3H9O4P/c1-5-8(4,6-2)7-3/h1-3H3

InChI key

WVLBCYQITXONBZ-UHFFFAOYSA-N



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pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Muta. 1B - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

224.6 °F

flash_point_c

107 °C

Regulatory Information

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R V Banerjee et al.
Biochemistry, 27(25), 9062-9070 (1988-12-13)
The transfer of 17O and/or 18O from (COOH-17O or -18O) enriched substrates to inorganic phosphate (Pi) has been demonstrated for two enzyme-catalyzed reactions involved in folate biosynthesis and glutamylation. COOH-18O-labeled folate, methotrexate, and dihydropteroate, in addition to [17O]-glutamate, were synthesized
Daniel Z Brunengraber et al.
Analytical biochemistry, 306(2), 278-282 (2002-07-19)
We have developed an assay for determining the 18O enrichment of water in biological fluids. Urine, plasma, or whole blood is reacted with phosphorous pentachloride to yield phosphoric acid. Derivatization of phosphoric acid with diazomethane generates trimethyl phosphate. The enrichment
K Sundararajan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(10), 1855-1867 (2000-09-16)
Trimethyl phosphate (TMP) and acetylene were codeposited in nitrogen and argon matrices and adducts of these species were identified using infrared spectroscopy. Formation of the adducts was evidenced by shifts in the vibrational frequencies of the modes involving the TMP



Global Trade Item Number

SKUGTIN
30-4640-5-500ML-J04061837743214