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Merck
CN

09682

Ammonia

puriss., anhydrous, ≥99.95%

Synonym(s):

Ammonia gas

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About This Item

Linear Formula:
NH3
CAS Number:
Molecular Weight:
17.03
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
231-635-3
Beilstein/REAXYS Number:
3587154
MDL number:
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Product Name

Ammonia, puriss., anhydrous, ≥99.95%

InChI key

QGZKDVFQNNGYKY-UHFFFAOYSA-N

InChI

1S/H3N/h1H3

SMILES string

N

vapor density

0.6 (vs air)

vapor pressure

8.75 atm ( 21 °C)

grade

puriss.

assay

≥99.95%

autoignition temp.

1203 °F

expl. lim.

25 %

impurities

≤0.01% water

bp

−33 °C (lit.)

mp

−78 °C (lit.)

Quality Level

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Application

Ammonia gas is a common reagent or reactant in the synthesis of variety of nitrogen containing inorganic compounds and organic intermediates. It is either used directly in gas phase reaction or bubbled through the reaction mixture.
  • Ammonia can be used in the direct synthesis of primary amines from alcohols.
  • Synthesis of N-doped graphene by vapor deposition in the presence of ammonia gas has been reported.

Other Notes

Recommended DIN 477 - Nr. 6
Sales restrictions may apply

Packaging

Cylinder with net ~1 kg

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Gas 2 - Press. Gas Liquefied gas - Skin Corr. 1B

supp_hazards

Storage Class

2A - Gases

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Ammonia.
Ullmann's Encyclopedia of Industrial Chemistry (2006)
Selective synthesis of primary amines directly from alcohols and ammonia.
Gunanathan C and Milstein D
Angewandte Chemie (International Edition in English), 47(45), 8661-8664 (2008)
Synthesis of N-doped graphene by chemical vapor deposition and its electrical properties.
Wei D, et al.
Nano Letters, 9(5), 1752-1758 (2009)
Liangti Qu et al.
ACS nano, 4(3), 1321-1326 (2010-02-17)
Nitrogen-doped graphene (N-graphene) was synthesized by chemical vapor deposition of methane in the presence of ammonia. The resultant N-graphene was demonstrated to act as a metal-free electrode with a much better electrocatalytic activity, long-term operation stability, and tolerance to crossover
Patrick M Erwin et al.
The ISME journal, 8(3), 575-588 (2013-10-25)
Ascidians are ecologically important components of marine ecosystems yet the ascidian microbiota remains largely unexplored beyond a few model species. We used 16S rRNA gene tag pyrosequencing to provide a comprehensive characterization of microbial symbionts in the tunic of 42

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