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Merck
CN

09935

Ammonium pyrrolidinedithiocarbamate

≥98.0% (NT), powder with lumps, puriss. p.a.

Synonym(s):

1-Pyrrolidinecarbodithioic acid ammonium salt, APDC, Ammonium pyrrolidinecarbodithioate, PDC, PDTC

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About This Item

Linear Formula:
C5H9NS2 · NH3
CAS Number:
Molecular Weight:
164.29
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
225-834-4
MDL number:
Beilstein/REAXYS Number:
3730472
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Product Name

Ammonium pyrrolidinedithiocarbamate, purum p.a., ≥98.0% (NT)

grade

purum p.a.

Quality Level

assay

≥98.0% (NT)

form

(powder or powder with lumps)

mp

153-155 °C (lit.)

cation traces

Bi: ≤10 mg/kg, Ca: ≤10 mg/kg, Cd: ≤10 mg/kg, Co: ≤10 mg/kg, Cr: ≤10 mg/kg, Cu: ≤10 mg/kg, Fe: ≤10 mg/kg, K: ≤50 mg/kg, Mg: ≤10 mg/kg, Mn: ≤10 mg/kg, Na: ≤50 mg/kg, Ni: ≤10 mg/kg, Pb: ≤10 mg/kg, Zn: ≤10 mg/kg

SMILES string

N.SC(=S)N1CCCC1

InChI

1S/C5H9NS2.H3N/c7-5(8)6-3-1-2-4-6;/h1-4H2,(H,7,8);1H3

InChI key

MDDIUTVUBYEEEM-UHFFFAOYSA-N

Gene Information

human ... RELA(5970)

Application

for the precipitation of As, Bi, Cd, Co, Cu, Fe, Mn, Ni, Pb, Sb, Sn, V, Zn from acidic solutions

Other Notes

Reagent used for the extraction and pre-concentration of heavy metals with an organic solvent from aqueous solutions for atomic absorption spectroscopy, AAS. MIBK (methyl isobutyl ketone) is the solvent of choice; The extract can be directly injected into the flame


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Determination of arsenic (III), arsenic (V), antimony (III), antimony (V), selenium (IV) and selenium (VI) by extraction with ammonium pyrrolidinedithiocarbamate-methyl isobutyl ketone and electrothermal atomic absorption spectrometry.
Subramanian KS and Meranger JC.
Analytica Chimica Acta, 124(1), 131-142 (1981)
B. Welz
Atomabsorptionsspektrometrie (1983)
J.D. Kinrade et al.
Analytical Chemistry, 46, 1894-1894 (1974)



Global Trade Item Number

SKUGTIN
09935-1KG04061838658432
09935-25G04061835554034
09935-100G04061838658425