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14765

Thallium(I) acetate

≥97.0%, solid

Synonym(s):

TlOAc, Acetic acid thallium(I) salt

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About This Item

Linear Formula:
CH3COOTl
CAS Number:
563-68-8
Molecular Weight:
263.43
NACRES:
NA.22
PubChem Substance ID:
57647193
UNSPSC Code:
12161600
EC Number:
209-257-5
MDL number:
MFCD00013045
Beilstein/REAXYS Number:
3693914
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Product Name

Thallium(I) acetate, purum, ≥97.0%

grade

purum

Quality Level

200

assay

≥97.0%

form

solid

reaction suitability

core: thallium, reagent type: catalyst

SMILES string

CC(=O)O[Tl]

InChI

1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

InChI key

HQOJMTATBXYHNR-UHFFFAOYSA-M

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General description

Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions.

Application

  • Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

铊类化学品
危险化学品

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP3784
BCCN1093
BCCM9606
BCCL9073
BCCK0233

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Thies, R.W.; Boop, J. L. et al
The Journal of Organic Chemistry, 48, 2021-2021 (1983)
The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Tanaka S, et al.
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
Tanabe T, et al.
ECS Transactions, 13(20), 7-7 (2008)
Grigg, R.; Kennewell, P. et al
Tetrahedron Letters, 33, 7789-7789 (1992)
M Csicsaky et al.
Toxicology, 49(1), 121-129 (1988-04-01)
The toxic effect of thallium added to the bath solution was studied with intra- and extracellular recordings from mammalian nerve-muscle preparations. To elucidate the target region, 3 different functional parameters were studied: (1) Post-synaptic endplate potentials (EPPs) resulting from evoked
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Global Trade Item Number

SKUGTIN
14765-25G04061833416563
14765-100G04061833380499

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