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15716

Boron trifluoride-methanol solution

~10% (~1.3 M), derivatization grade (GC derivatization), LiChropur™

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About This Item

Linear Formula:
BF3 · MeOH
CAS Number:
373-57-9
Molecular Weight:
99.85
UNSPSC Code:
12352104
NACRES:
NA.05
PubChem Substance ID:
329750982
EC Number:
206-766-4
Beilstein/REAXYS Number:
3611499
MDL number:
MFCD00071635
Concentration:
~10% (~1.3 M)
Form:
liquid
Grade:
derivatization grade (GC derivatization)
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grade

derivatization grade (GC derivatization)

Quality Level

100

product line

LiChropur™

form

liquid

quality

LiChropur™

reaction suitability

reagent type: derivatization reagent
reaction type: Esterifications

concentration

~10% (~1.3 M)

technique(s)

gas chromatography (GC): suitable

density

0.86 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

CO.FB(F)F

InChI

1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;

InChI key

JBXYCUKPDAAYAS-UHFFFAOYSA-N

General description

Boron trifluoride (BF3) is a Lewis acid; it is a very useful reagent for forming esters from acids. Boron trifluoride is commercially available as a 14% solution in methanol for forming esters derivatives. It catalysed reactions carried out in a water bath are very rapid and can be completed in a few minutes. Boron-trifluoride-catalysed transesterification of vegetable oils is one of the most popular methods. For transesterification of vegetable oils, BF3 is used in methanol (15 to 20% w/v).

Application

Boron trifluoride-methanol solution may be used for catalysing a method, used for the synthesis of bishydroperoxides and their derivatives, based on a reaction of ketals with a solution of hydrogen peroxide in anhydrous ether. It may also be used for the rapid preparation of fatty acid esters for gas chromatographic analysis, as it converts fatty acids to their respective methyl esters in about 2 minutes.
Learn more in the Product Information
Suitable for derivatization of hydroxy fatty acids.

Other Notes

Reagent for esterifying fatty acid for gas chromatographic analysis.
Reagent for methyl ester, O-acetyl.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

target_organs

Eyes,Central nervous system, Kidney

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

49.5 °F

flash_point_c

9.7 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP1792
BCCP2930
BCCN8136
BCCN4012
BCCN2248

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A new method for the synthesis of bishydroperoxides based on a reaction of ketals with hydrogen peroxide catalyzed by boron trifluoride complexes.
Alexander TO
Tetrahedron Letters, 44 (39), 7359-7363 (2003)
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Global Trade Item Number

SKUGTIN
15716-10X1ML04061837683121
15716-1L04061838743220
15716-100ML04061838743206
15716-250ML04061837810619
15716-10ML04061838743213
15716-1ML04061837683138