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About This Item
Linear Formula:
CH3C(=NOH)C(=NOH)CH3
CAS Number:
Molecular Weight:
116.12
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-420-1
MDL number:
Beilstein/REAXYS Number:
506731
Assay:
≥99%
Form:
powder
Product Name
Dimethylglyoxime, ACS reagent, ≥99%, powder
grade
ACS reagent
Quality Segment
assay
≥99%
form
powder
impurities
≤0.05% insol. Alcohol
ign. residue
≤0.05%
mp
240-241 °C (lit.)
suitability
passes test for determination of nickel
functional group
amine, oxime
SMILES string
CC(=N/O)\C(C)=N\O
InChI
1S/C4H8N2O2/c1-3(5-7)4(2)6-8/h7-8H,1-2H3/b5-3+,6-4+
InChI key
JGUQDUKBUKFFRO-GGWOSOGESA-N
General description
Dimethylglyoxime(DMG) is a complexing ligand. Dimethylglyoxime forms a number of mixed ligand complexes with N-acetylglycine and various metals such as VO(IV), Ni(II), Zn(II), Pd(II), Cd(II) and Pb(II).
Application
Dimethylglyoxime (DMG) may be used as complexing agent for the quantification of metallic imprurities [cobalt(II) and nickel(II)] in brine (5.5mol/l aqueous solution of sodium chloride) by adsorptive stripping voltammetry. It may be used in the preparation of nickel dimethylglyoxime, a dye complex used for the fabrication of dye-sensitized solar cells.
Dimethylglyoxime may be used as a chelating agent for determining nickel ion in complexes by gravimetric, titrimetric or colorimetric analysis.
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signalword
Warning
hcodes
Hazard Classifications
Flam. Sol. 2
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Related Content
The basis of the selectivity of dimethylglyoxime as a reagent in gravimetric analysis.
Sharpe AG and Wakefield DB
Journal of the Chemical Society, 281-285 (1957)
Nile Blue and Nickel Organometallic Dyes Applied in Dye-sensitized Solar Cells.
Siami E, et al.
Portugaliae Electrochimica Acta , 33(1), 23-33 (2015)
Chelating agents in nonaqueous titrimetry.
Brummet BD and Hollweg RM
Analytical Chemistry, 28(4), 448-450 (1956)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| GW21358-50UG | 04061837818165 |
| 162574-100G | 04061838747099 |
| 162574-500G | 04061838747105 |
