18105
3-Bromo-1,2-propanediol
technical, ≥96% (GC)
Synonym(s):
α-Glycerol bromohydrin
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About This Item
Linear Formula:
CH2BrCHOHCH2OH
CAS Number:
Molecular Weight:
154.99
EC Number:
225-186-2
UNSPSC Code:
12162002
PubChem Substance ID:
Beilstein/REAXYS Number:
1719124
MDL number:
InChI key
SIBFQOUHOCRXDL-UHFFFAOYSA-N
InChI
1S/C3H7BrO2/c4-1-3(6)2-5/h3,5-6H,1-2H2
SMILES string
OCC(O)CBr
grade
technical
assay
≥96% (GC)
bp
72-75 °C/0.2 mmHg (lit.)
density
1.771 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Other Notes
Protecting group reagent for carbonyl functions.; The bromomethylethylene ketals can be cleaved under neutral conditions
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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E.J. Corey et al.
The Journal of Organic Chemistry, 38, 834-834 (1973)
A R Jones et al.
Journal of applied toxicology : JAT, 16(1), 57-63 (1996-01-01)
(R,S)- and (R)-3-Bromopropan-1,2-diol (alpha-bromohydrin) produced diuresis and glucosuria when administered to male rats but had no effect on the metabolic activity of rat kidney tubules in vitro. The oxidation products (R,S)-3-bromolactate and 3-bromopyruvate produced brief phases of diuresis but not
A R Jones et al.
Journal of reproduction and fertility, 108(1), 95-100 (1996-09-01)
Boar spermatozoa incubated with glycerol 3-phosphate as substrate produced CO2 and an accumulation of dihydroxyacetone phosphate and fructose-1,6-bisphosphate. The rate of oxidation of glycerol 3-phosphate was decreased, as was the production of CO2 and the two glycolytic intermediates, in the
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