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Merck
CN

19533

Geranyl pyrophosphate lithium salt

analytical standard

Synonym(s):

(E)-3,7-Dimethyl-2,6-octadien-1-ol trihydrogen pyrophosphate lithium salt, (E)-3,7-Dimethyl-2,6-octadien-1-yl pyrophosphate lithium salt, GPP-Li

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About This Item

Empirical Formula (Hill Notation):
C10H20O7P2 · xLi+
CAS Number:
21141-43-5
Molecular Weight:
314.21 (free acid basis)
MDL number:
MFCD18827619
UNSPSC Code:
85151701
NACRES:
NA.24
Beilstein/REAXYS Number:
1915690

Key Documents

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Product Name

Geranyl pyrophosphate lithium salt, analytical standard

grade

analytical standard

assay

≥95.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

food and beverages

format

neat

shipped in

dry ice

storage temp.

−20°C

Quality Level

100

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Analysis Note

NMR-Internal Standard : KHP

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0679
BCCM8450
BCCM7781
BCCJ4498
BCCG9125

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Ken'ichi Hagiwara et al.
Biochemistry, 43(2), 300-309 (2004-01-14)
Farnesylation of the gamma-subunit of the retinal G-protein, transducin (Talpha/Tbetagamma), is indispensable for light-initiated signaling in photoreceptor cells. However, the farnesyl-mediated molecular interactions important for signaling are not well understood. To explore this issue, we created a functional Tbetagamma analogue
Tao-Hsin Chang et al.
The Plant cell, 22(2), 454-467 (2010-02-09)
Terpenes (isoprenoids), derived from isoprenyl pyrophosphates, are versatile natural compounds that act as metabolism mediators, plant volatiles, and ecological communicators. Divergent evolution of homomeric prenyltransferases (PTSs) has allowed PTSs to optimize their active-site pockets to achieve catalytic fidelity and diversity.
Axel Schmidt et al.
Plant physiology, 152(2), 639-655 (2009-11-27)
The conifer Picea abies (Norway spruce) defends itself against herbivores and pathogens with a terpenoid-based oleoresin composed chiefly of monoterpenes (C(10)) and diterpenes (C(20)). An important group of enzymes in oleoresin biosynthesis are the short-chain isoprenyl diphosphate synthases that produce
Orapin Ariyawutthiphan et al.
Acta crystallographica. Section F, Structural biology and crystallization communications, 67(Pt 3), 417-420 (2011-03-12)
The biosynthetic pathway of the off-flavour terpenoid alcohol 2-methylisoborneol (2-MIB) requires geranyl pyrophosphate methyltransferase (GPPMT) to methylate GPP before the cyclization reaction. GPPMT is the first example of an S-adenosyl-L-methionine-dependent methyltransferase that acts on general intermediates such as geranyl pyrophosphate
Kuan-Hung Chen et al.
The Journal of organic chemistry, 74(2), 895-898 (2008-12-04)
Hexaamide receptor 4 and coumarin phosphate 5 form an ensemble for effective sensing of geranyl pyrophosphate (GPP). Fluorescence resonance energy transfer in the 4 + 5 ensemble diminishes when 5 is replaced by GPP. Receptor 4 binds selectively with GPP
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