20370
tert-Butyl nitrite
technical, ≥90% (GC)
Synonym(s):
1,1-Dimethylethyl nitrite
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About This Item
Linear Formula:
(CH3)3CONO
CAS Number:
Molecular Weight:
103.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-757-0
Beilstein/REAXYS Number:
1209339
MDL number:
Assay:
≥90% (GC)
Form:
liquid
grade
technical
Quality Level
assay
≥90% (GC)
form
liquid
impurities
≤8% tert-butyl alcohol
refractive index
n20/D 1.368
bp
61-63 °C (lit.)
solubility
alcohol: very soluble, chloroform: very soluble, diethyl ether: very soluble, glycerol: insoluble, water: slightly soluble
density
0.864 g/mL at 20 °C, 0.867 g/mL at 25 °C (lit.)
functional group
O-nitroso, nitroso
storage temp.
2-8°C
SMILES string
CC(C)(C)ON=O
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
General description
tert-Butyl nitrite is an organic building block widely used in various organic transformations such as oxidation, diazotization, nitrosation, nitration, oximation, N-synthon, and miscellaneous reactions.
Application
tert-Butyl nitrite can be used as a reactant to synthesize aryl diazonium salts via diazotation.
Other Notes
Reagent for nitrosations, kinetics; Clean source of Me3C radicals by near-UV photolysis
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
Regulatory Information
危险化学品
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L. Batt et al.
International Journal of Chemical Kinetics, 21, 535-535 (1989)
Brenden Kilpatrick et al.
Chemical communications (Cambridge, England), 49(5), 514-516 (2012-12-01)
A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially
Quantum defects as versatile anchors for carbon nanotube functionalization
Mann F, et al.
Nature Protocols, 17, 727-747 (2022)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 20370-500ML-F | 04061836825683 |
| 20370-100ML-F | 04061838766229 |