vapor pressure
33 hPa (~429 °C)
Quality Level
Assay
≥99.99% trace metals basis
form
crystalline powder
flakes
reaction suitability
reagent type: catalyst
core: tin
pH
2.18 (20 °C)
bp
652 °C (lit.)
mp
246 °C (lit.)
SMILES string
Cl[SnH2]Cl
InChI
1S/2ClH.Sn/h2*1H;/q;;+2/p-2
InChI key
AXZWODMDQAVCJE-UHFFFAOYSA-L
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Related Categories
General description
- aromatic nitro compounds
- nitriles
- cyanosilyl ethers
- organic azides
Application
- To catalyze the addition of diazo sulfones, diazo phosphine oxides and diazo phosphonates to aldehydes to form β-keto sulfones, β-keto phosphine oxides and β-keto phosphonates, respectively.
- Along with trityl chloride, to catalyze the aldol reaction of silyl enol ethers with acetals or aldehydes and the Michael reaction of silyl enol ethers with α,β-unsaturated ketones.
- As a promoter in the allylic amination of allylic alcohols with amines in the presence of palladium catalyst.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
Target Organs
Cardio-vascular system, Respiratory system
Storage Class Code
8B - Non-combustible, corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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