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Merck
CN

21360

(+)-Camphor-10-sulfonic acid

purum, ≥98.0% (T)

Synonym(s):

(+)-β-Camphorsulfonic acid, (1S)-(+)-Camphor-10-sulfonic acid

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About This Item

Empirical Formula (Hill Notation):
C10H16O4S
CAS Number:
Molecular Weight:
232.30
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-554-1
Beilstein/REAXYS Number:
2809675
MDL number:
Assay:
≥98.0% (T)
Form:
solid
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grade

purum

Quality Segment

assay

≥98.0% (T)

form

solid

optical activity

[α]20/D +21.5±1°, c = 10% in H2O

mp

~200 °C (dec.) (lit.)

functional group

ketone, sulfonic acid

SMILES string

[H][C@@]12CC[C@@](CS(O)(=O)=O)(C(=O)C1)C2(C)C

InChI

1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1

InChI key

MIOPJNTWMNEORI-GMSGAONNSA-N

Application

(+)-Camphor-10-sulfonic acid may be used as a starting material to synthesize 10-iodocamphor. (±)-S-methyl-S-phenylsulfoximine can be resolved using it as a chiral resolving agent to form the (-)-form in high enantiomeric purity. Polyaniline (PAni) doped with (+)-camphor-10-sulfonic acid forms electrically conductive polymer nanofibers, which are excellent ammonia gas sensors.

Other Notes

Reagent used for the resolution of bases; use as mobile phase additive for LC separations; Reagent used for crystallization-induced asymmetric transformations


pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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