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24260

Chlorodicyclohexylborane solution

Name: Chlorodicyclohexylborane solution
Brand: SIAL

purum, ~1 M in hexane

Synonym(s):

Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane

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About This Item

Linear Formula:

(C₆H₁₁)₂BCl

CAS Number:

36140-19-9

Molecular Weight:

212.57

PubChem Substance ID:

24854571

UNSPSC Code:

12352000

Beilstein/REAXYS Number:

3233942

MDL number:

MFCD00191906

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Properties

grade

purum

reaction suitability

reagent type: reductant

concentration

~1 M in hexane

density

0.74 g/mL at 20 °C

SMILES string

ClB(C1CCCCC1)C2CCCCC2

InChI

1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2

InChI key

PBBOKJIYEZCTEH-UHFFFAOYSA-N

Description

Application

Reactant for:

Aldol addition reactions
Mukaiyama aldol addition
Microwave assisted ring closing metathesis reactions
C-alkylation of aromatic aldimines
Reversible ketone-ketone aldol reactions
Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

Other Notes

Ideal reagent for the generation of E-enol borinates from ketones in high stereoselectivity

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