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31258

Aldicarb-sulfoxide

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C7H14N2O3S
CAS Number:
1646-87-3
Molecular Weight:
206.26
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329753707
MDL number:
MFCD00143566
Beilstein/REAXYS Number:
2212914
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grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CNC(ON=CC(C)(C)S(C)=O)=O

InChI

1S/C7H14N2O3S/c1-7(2,13(4)11)5-9-12-6(10)8-3/h5H,1-4H3,(H,8,10)

InChI key

BXPMAGSOWXBZHS-UHFFFAOYSA-N

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General description

Aldicarb sulfoxide, cholinesterase inhibitor in insects, is formed from Temik during initial oxidation. It is persistent in soil and is rapidly translocated in plants.

Application

Aldicarb-sulfoxide may be used as a pesticide reference standard for the determination of the analyte in:
  • Fruits and vegetable using solid-phase extraction followed by liquid chromatography-atmospheric pressure chemical ionization mass spectrometry.
  • Water samples by gas chromatography/mass spectrometry (GC-MS) using short capillary columns.
  • Foodstuffs by liquid chromatography-tandem mass spectrometry (LC-MS/MS) using a triple quadrupole analyzer.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

hcodes

H300,H400

Hazard Classifications

Acute Tox. 1 Oral - Aquatic Acute 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ8058
BCCF6046
BCCF0558
BCCB4513
BCBZ6039

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Application of matrix solid phase dispersion to the determination of imidacloprid, carbaryl, aldicarb, and their main metabolites in honeybees by liquid chromatography-mass spectrometry detection.
Totti S
Talanta, 69(3), 724-729 (2006)
M Pelekis et al.
Xenobiotica; the fate of foreign compounds in biological systems, 27(11), 1113-1120 (1997-12-31)
1. The rate of sulphoxidation of aldicarb (2-methyl-2-(methylthio) propanal O-[(methylamino) carbonyl oxime], Temik) in rat hepatic, renal and pulmonary microsomes was determined by quantitating the levels of aldicarb sulphoxide and aldicarb sulphone produced during incubations. Under in vitro experimental conditions
Behavioral Responses of Heterodera rostochiensis Larvae to Aldicarb and its Sulfoxide and Sulfone.
Nelmes AJ.
Journal of Nematology, 2(3), 223-227 (1970)
High performance liquid chromatographic method for the determination of aldicarb sulfoxide in watermelon.
K C Ting et al.
Bulletin of environmental contamination and toxicology, 37(2), 192-198 (1986-08-01)
L R Goldman et al.
Archives of environmental health, 45(3), 141-147 (1990-05-01)
Three outbreaks of food poisoning involving watermelons or cucumbers and caused by the carbamate pesticide aldicarb occurred in California between 1985 and 1988. For each outbreak, and for an outbreak of aldicarb poisoning associated with English cucumbers previously reported in
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Global Trade Item Number

SKUGTIN
31258-100MG04061835511365

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