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Merck
CN

31461

Carbophenothion

PESTANAL®, analytical standard

Synonym(s):

S-(4-Chlorophenylthiomethyl) O,O-diethyl phosphorodithioate

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About This Item

Empirical Formula (Hill Notation):
C11H16ClO2PS3
CAS Number:
786-19-6
Molecular Weight:
342.87
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329753775
EC Number:
212-324-1
Beilstein/REAXYS Number:
1885240
MDL number:
MFCD00128009

Key Documents

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InChI key

VEDTXTNSFWUXGQ-UHFFFAOYSA-N

InChI

1S/C11H16ClO2PS3/c1-3-13-15(16,14-4-2)18-9-17-11-7-5-10(12)6-8-11/h5-8H,3-4,9H2,1-2H3

SMILES string

CCOP(=S)(OCC)SCSc1ccc(Cl)cc1

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

Quality Level

100

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General description

Carbophenothion is an organophosphorus pesticide which is highly toxic through ingestion as well as skin absorption. It is mostly used as non-systemic insecticide and acaricide.

Application

Carbophenothion may have been used as internal standard for identification and characterisation of organochlorine and organophosphorus pesticides in Brazil′s medicinal plants like Passiflora L. using high-resolution gas chromatography with electron-capture and flame photometric detection (HRGC–ECD/FPD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

农药列管产品
危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCL8110
BCCJ1103
BCBW3097

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Fast supercritical fluid extraction and high-resolution gas chromatography with electron-capture and flame photometric detection for multiresidue screening of organochlorine and organophosphorus pesticides in Brazil's medicinal plants.
Zuin VG, Yariwake JH, Bicchi C.
Journal of Chromatography A, 985(1-2), 159-166 (2003)
T.S.S. Dikshith
Handbook of Chemicals and Safety, 167-167 (2016)
Evaluation of organophosphorus pesticide residues in citrus fruits from the Valencian community (Spain).
Torres CM
Journal of AOAC (Association of Official Analytical Chemists) International, 80(5), 1122-1128 (1997)
J R Clark et al.
Ecotoxicology and environmental safety, 10(3), 382-390 (1985-12-01)
The acute toxicity (96-hr LC50) of carbophenothion, chlorpyrifos, and fenvalerate to six estuarine fishes was determined in flow-through laboratory tests. The atherinid fishes (Menidia menidia, M. peninsulae, M. beryllina, and Leuresthes tenuis) consistently were among the most sensitive species tested
Dislodgeable residues of carbophenothion in Florida citrus: implications for safe worker reentry.
G C de Batista et al.
Bulletin of environmental contamination and toxicology, 35(2), 213-221 (1985-08-01)
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