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Merck
CN

31477

Bifenox

PESTANAL®, analytical standard

Synonym(s):

Methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate

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About This Item

Empirical Formula (Hill Notation):
C14H9Cl2NO5
CAS Number:
42576-02-3
Molecular Weight:
342.13
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329753781
EC Number:
255-894-7
Beilstein/REAXYS Number:
2170169
MDL number:
MFCD00055314

Key Documents

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InChI

1S/C14H9Cl2NO5/c1-21-14(18)10-7-9(3-4-12(10)17(19)20)22-13-5-2-8(15)6-11(13)16/h2-7H,1H3

InChI key

SUSRORUBZHMPCO-UHFFFAOYSA-N

SMILES string

COC(=O)c1cc(Oc2ccc(Cl)cc2Cl)ccc1[N+]([O-])=O

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Warning

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

pictograms

Exclamation markEnvironment
GHS07,GHS09

hcodes

H302,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCN9579
BCCG7167
BCCG1877
BCBV2018
BCBT5092

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Ana Catarina Almeida et al.
Aquatic toxicology (Amsterdam, Netherlands), 210, 117-128 (2019-03-09)
The widespread presence of herbicides in the aquatic environment has raised awareness about the need to develop further in depth ecotoxicological risk assessments, more specifically on potential effects on photosynthetic organisms as microalgae. The majority of the information available regarding
K Siviková et al.
Mutation research, 439(2), 129-135 (1999-02-19)
The commercial herbicide with active element bifenox (principal tradename Modown) was tested for the evaluation of genotoxicity in cultured cow peripheral lymphocytes in vitro. Several cytogenetic endpoints as chromosome aberrations (CA), sister chromatid exchanges (SCE), mitotic (MI) and proliferation (PI)
D J Hoffman et al.
Journal of toxicology and environmental health, 34(3), 323-336 (1991-11-01)
Beginning the day after hatching, American kestrel (Falco sparverius) nestlings were orally dosed for 10 consecutive days with 5 microliters/g of corn oil (controls) or one of the diphenyl ether herbicides (nitrofen, bifenox, or oxyfluorfen) at concentrations of 10, 50
A Lubineau et al.
Carbohydrate research, 228(1), 191-203 (1992-04-10)
Glycosides (alpha- and beta-D-glucosides and -D-galactosides) derived from three pesticides, 2-tert-butyl-2,4-dinitrophenol,2,6-dibromo-4-cyanophenol, and 5-(2,4-dichlorophenoxy)-2-nitrobenzoic acid, were synthesized from 2,3,4,6-tetra-O-chloroacetyl-D-gluco- and -D-galactopyranose by use of the Mitsunobu reaction. It was shown that selectivity for the beta-D anomer increases with the pKa of
H Jinno et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 37(1), 69-74 (1999-03-09)
We studied the cytotoxic and porphyrinogenic effects of four diphenyl ethers (DPEs), chlornitrofen (CNP), CNP-amino, chlomethoxyfen and bifenox, in rat hepatocytes cultured on Matrigel. Cytotoxicity was determined as a decrease in viability measured by the release of lactate dehydrogenase. Of
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