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Merck
CN

31597

o-Anisidine

analytical standard

Synonym(s):

2-Aminoanisole, 2-Methoxyaniline

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About This Item

Linear Formula:
CH3OC6H4NH2
CAS Number:
Molecular Weight:
123.15
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
201-963-1
Beilstein/REAXYS Number:
386210
MDL number:
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Product Name

o-Anisidine, analytical standard

InChI key

VMPITZXILSNTON-UHFFFAOYSA-N

InChI

1S/C7H9NO/c1-9-7-5-3-2-4-6(7)8/h2-5H,8H2,1H3

SMILES string

COc1ccccc1N

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.574 (lit.)

bp

225 °C (lit.)

mp

3-6 °C (lit.)

density

1.092 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

Quality Level

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Disclaimer

Restricted to professional users. Attention − Avoid exposure − obtain special instructions before use.

General description

This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

pictograms

Skull and crossbonesHealth hazard

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Muta. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

212.0 °F - closed cup

flash_point_c

100 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Xin-Gui Li et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(18), 4573-4581 (2009-03-20)
The highest Hg-ion adsorbance so far, namely up to 2063 mg g(-1), has been achieved by poly(aniline-co-5-sulfo-2-anisidine) nanosorbents. Sorption of Hg ions occurs mainly by redox and chelation mechanisms (see scheme), but also by ion exchange and physisorption.Poly(aniline (AN)-co-5-sulfo-2-anisidine (SA))
M Mazur
The European physical journal. E, Soft matter, 22(1), 67-75 (2007-03-06)
We report on chemical polymerization of two aniline derivatives - 2-methylaniline and 2-methoxyaniline -- in a two-phase water/pentane system. We have found that poly(2-methylaniline) is produced in form of an amorphous material regardless of the fact whether the monomer is
Arnab Dawn et al.
The journal of physical chemistry. B, 110(37), 18291-18298 (2006-09-15)
A novel nano-biocomposite of silver and poly(o-methoxy aniline) (POMA)/DNA hybrid has been prepared by adding DNA solution to an aqueous solution of POMA (emeraldine base, EB) and AgNO(3) mixture. The mixture was aged for 10 days and was freeze-dried to
P Santhosh et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 59(7), 1427-1439 (2003-04-26)
UV-visible spectroelectrochemical studies on copolymerization of diphenylamine (DPA) with ortho-methoxy aniline (OMA) were carried out for different feed ratios of DPA and OMA using indium tin oxide (ITO)-coated glass as working electrode. The UV-visible spectra show clear dependencies on the
Parimal Routh et al.
Biophysical chemistry, 143(3), 145-153 (2009-06-02)
Biomolecular hybrids of a conducting polymer [poly(o-methoxy aniline) (POMA)] and RNA are prepared at the three different compositions by mixing aqueous solutions of diethyl, 2-hydroxy ethyl, ammonium salt of RNA (type IX from Torula Yeast) and POMA (ES, emeraldine salt;

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