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Merck
CN

31597

o-Anisidine

analytical standard

Synonym(s):

2-Aminoanisole, 2-Methoxyaniline

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About This Item

Linear Formula:
CH3OC6H4NH2
CAS Number:
90-04-0
Molecular Weight:
123.15
Beilstein:
386210
EC Number:
201-963-1
MDL number:
MFCD00007688
UNSPSC Code:
41116107
PubChem Substance ID:
329753842
NACRES:
NA.24

Key Documents

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grade

analytical standard

Quality Level

100

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.574 (lit.)

bp

225 °C (lit.)

mp

3-6 °C (lit.)

density

1.092 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

COc1ccccc1N

InChI

1S/C7H9NO/c1-9-7-5-3-2-4-6(7)8/h2-5H,8H2,1H3

InChI key

VMPITZXILSNTON-UHFFFAOYSA-N

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General description

This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Disclaimer

Restricted to professional users. Attention − Avoid exposure − obtain special instructions before use.

Pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Muta. 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

212.0 °F - closed cup

Flash Point(C)

100 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCF8395
BCBT3585
BCBR8680V

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P Santhosh et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 59(7), 1427-1439 (2003-04-26)
UV-visible spectroelectrochemical studies on copolymerization of diphenylamine (DPA) with ortho-methoxy aniline (OMA) were carried out for different feed ratios of DPA and OMA using indium tin oxide (ITO)-coated glass as working electrode. The UV-visible spectra show clear dependencies on the
Arnab Dawn et al.
The journal of physical chemistry. B, 110(37), 18291-18298 (2006-09-15)
A novel nano-biocomposite of silver and poly(o-methoxy aniline) (POMA)/DNA hybrid has been prepared by adding DNA solution to an aqueous solution of POMA (emeraldine base, EB) and AgNO(3) mixture. The mixture was aged for 10 days and was freeze-dried to
M Mazur
The European physical journal. E, Soft matter, 22(1), 67-75 (2007-03-06)
We report on chemical polymerization of two aniline derivatives - 2-methylaniline and 2-methoxyaniline -- in a two-phase water/pentane system. We have found that poly(2-methylaniline) is produced in form of an amorphous material regardless of the fact whether the monomer is
Ning Wang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(19), 6049-6054 (2012-03-29)
The recent development of 1D nanomaterials of controllable size, composition, and structure has opened up enormous possibilities for engineering catalysts with enhanced activity and selectivity. Herein, we report a one-step strategy for the fabrication of versatile silver nanomaterials. Tailored structures
Marie Stiborová et al.
International journal of cancer, 116(5), 667-678 (2005-04-14)
2-methoxyaniline (o-anisidine) is an industrial and environmental pollutant and a bladder carcinogen for rodents. The mechanism of its carcinogenicity was investigated with 2 independent methods, 32P-postlabeling and 14C-labeled o-anisidine, to show that o-anisidine binds covalently to DNA in vitro after
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