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31730

Diethylamine

≥99.5% (GC), liquid, puriss. p.a.

Synonym(s):

N,N-Diethylamine, N-ethyl-ethanamine, DEA, Diethamine, Diethyl amine

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About This Item

Linear Formula:
(C2H5)2NH
CAS Number:
109-89-7
Molecular Weight:
73.14
NACRES:
NA.21
PubChem Substance ID:
57648605
UNSPSC Code:
12352100
EC Number:
203-716-3
MDL number:
MFCD00009032
Beilstein/REAXYS Number:
605268
Assay:
≥99.5% (GC)
Form:
liquid
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Product Name

Diethylamine, puriss. p.a., ≥99.5% (GC)

vapor density

2.5 (vs air)

Quality Segment

vapor pressure

14.14 psi ( 55 °C), 180 mmHg ( 20 °C), 3.51 psi ( 20 °C)

grade

puriss. p.a.

assay

≥99.5% (GC)

form

liquid

autoignition temp.

594 °F

expl. lim.

10.1 %

impurities

≤0.1% water

evapn. residue

≤0.001%

refractive index

n20/D 1.385 (lit.), n20/D 1.386

bp

55 °C (lit.)

mp

−50 °C (lit.)

density

0.707 g/mL at 25 °C (lit.)

cation traces

Al: ≤0.5 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, K: ≤0.5 mg/kg, Li: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Mo: ≤0.1 mg/kg, Na: ≤0.5 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.1 mg/kg, Sr: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg

SMILES string

CCNCC

InChI

1S/C4H11N/c1-3-5-4-2/h5H,3-4H2,1-2H3

InChI key

HPNMFZURTQLUMO-UHFFFAOYSA-N

General description

Diethylamine is a secondary amine that is used in the production of pesticides, dyes, rubber, resins, and pharmaceuticals as a solvent, catalyst, and corrosion inhibitor.

Application

Diethylamine can be used as:
  • A catalyst in the tandem Knoevenagel-Michael reaction of dimedone with aromatic aldehydes to synthesize bis-dimedone derivatives.
  • A solvent to synthesize 4-quinolones via Sonogashira cross-coupling of iodoanilines and alkynes.
  • A base in the desymmetrizing cyclization of benzylic diallyl iodide to synthesize methylene indanes via intramolecular Heck reaction.
  • A template in the synthesis of silicoaluminophosphate (SAPO) molecular sieves.

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Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

Target Organs

Respiratory system

Storage Class

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

-14.8 °F - closed cup

Flash Point (°C)

-26 °C - closed cup

PPE (personal protective equipment)

Faceshields, Gloves, Goggles

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