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Emamectin benzoate

PESTANAL®, analytical standard

Synonym(s):

(4′’R)-4″-Deoxy-4″-(methylamino)avermectin B1 benzoate

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About This Item

CAS Number:
155569-91-8
UNSPSC Code:
41116107
NACRES:
NA.24
MDL number:
MFCD01757274
Technical Service
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grade

analytical standard

Quality Segment

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

format

neat

SMILES string

[N+H2]([C@H]2[C@@H](O[C@H](C[C@@H]2OC)O[C@H]3[C@@H](O[C@H](C[C@@H]3OC)O[C@H]4[C@H](\C=C\C=C5\[C@@]6([C@H](OC\5)[C@@H](C(=C[C@H]6C(=O)O[C@@H]7C[C@]8(O[C@@H](C7)C\C=C\4/C)O[C@@H]([C@H](C=C8)C)[C@H](CC)C)C)O)O)C)C)C)C.[O-]C(=O)c1ccccc1

InChI

1S/C49H75NO13.C7H6O2/c1-12-26(2)44-29(5)18-19-48(63-44)24-35-21-34(62-48)17-16-28(4)43(27(3)14-13-15-33-25-56-46-42(51)30(6)20-36(47(52)59-35)49(33,46)53)60-40-23-38(55-11)45(32(8)58-40)61-39-22-37(54-10)41(50-9)31(7)57-39;8-7(9)6-4-2-1-3-5-6/h13-16,18-20,26-27,29,31-32,34-46,50-51,53H,12,17,21-25H2,1-11H3;1-5H,(H,8,9)/b14-13+,28-16+,33-15+;/t26-,27-,29-,31-,32-,34+,35-,36-,37-,38-,39-,40-,41-,42+,43-,44+,45-,46+,48+,49+;/m0./s1

InChI key

GCKZANITAMOIAR-XWVCPFKXSA-N

General description

Emamectin benzoate is a macrocyclic insecticide found to be stable aqueous hydrolysis. Avermectin B1 can be the starting material synthesizing emamectin benzoate. In some occasions, it is used as acaricide for vegetables, fruits and cereals.

Application

Emamectin benzoate may be used as pesticide standard in supercritical fluid chromatography/tandem mass spectrometry (SFC/MS/MS) method for pesticide residue determination from brown rice, onion, and spinach samples.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT RE 1 - STOT SE 1

Target Organs

Nervous system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

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