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Merck
CN

32058

Pirimiphos-methyl

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C11H20N3O3PS
CAS Number:
29232-93-7
Molecular Weight:
305.33
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329753990
EC Number:
249-528-5
Beilstein/REAXYS Number:
755726
MDL number:
MFCD00055366

Key Documents

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Product Name

Pirimiphos-methyl, PESTANAL®, analytical standard

InChI key

QHOQHJPRIBSPCY-UHFFFAOYSA-N

InChI

1S/C11H20N3O3PS/c1-6-14(7-2)11-12-9(3)8-10(13-11)17-18(19,15-4)16-5/h8H,6-7H2,1-5H3

SMILES string

CCN(CC)c1nc(C)cc(OP(=S)(OC)OC)n1

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

Quality Level

100

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Application

PMM may have been used as reference standard for identification of possible intermediate products formed during photocatalytic degradation of PMM using different chromatographic methods, like GC, HPLC, GC-MS, TOC and LC-MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Pirimiphos-methyl (PMM) is an organophosphorous pesticide.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 1 - STOT SE 1

target_organs

Nervous system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCN9192
BCCF9905
BCBT5775

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Photocatalytic degradation of pesticide pirimiphos-methyl: Determination of the reaction pathway and identification of intermediate products by various analytical methods.
Herrmann, Jean Marie, et al.
Catalysis Today, 54.2, 353-367 (1999)
Michele Del Carlo et al.
Analytical and bioanalytical chemistry, 381(7), 1367-1372 (2005-03-05)
An electrochemical assay used for detecting acetylcholinesterase (AChE) inhibitors has been optimised to detect pirimiphos-methyl in durum wheat. Pirimiphos-methyl is a phosphothionate insecticide and so it needs to be transformed into the corresponding oxo form to act as an effective
Cédric Pennetier et al.
Malaria journal, 6, 38-38 (2007-03-31)
To manage the kdr pyrethroid-resistance in Anopheline malaria vectors, new compounds or new strategies are urgently needed. Recently, mixing repellents (DEET) and a non-pyrethroid insecticide (propoxur) was shown to be as effective as deltamethrin, a standard pyrethroid, under laboratory conditions
Luigi Lucini et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 46(6), 518-524 (2011-07-06)
The aim of this work was to comparatively assess the persistence of pirimiphos methyl residues in cereals and in their milling fractions after spray application in post harvest. An analytical method, based on a slightly modified QuEChERS extraction followed by
Darjaniva Molina et al.
Biomedica : revista del Instituto Nacional de Salud, 29(4), 604-615 (2010-05-05)
A study of insecticide resistance was undertaken at focal level in the localities Catuaro, Guayana, Platanito and Rio de Agua, Libertador County, Sucre State, Venezuela, a region with malaria transmission, where Anopheles aquasalis is the main vector. Insecticide resistance was
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