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Merck
CN

32060

Tolylfluanid

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C10H13Cl2FN2O2S2
CAS Number:
731-27-1
Molecular Weight:
347.26
EC Number:
211-986-9
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329753720
MDL number:
MFCD00055477
Colour Index Number:
45430
Beilstein/REAXYS Number:
2949607

Key Documents

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Product Name

Tolylfluanid, PESTANAL®, analytical standard

InChI key

HYVWIQDYBVKITD-UHFFFAOYSA-N

InChI

1S/C10H13Cl2FN2O2S2/c1-8-4-6-9(7-5-8)15(18-10(11,12)13)19(16,17)14(2)3/h4-7H,1-3H3

SMILES string

CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)c1ccc(C)cc1

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Tolylfluanid may be used as a reference standard for the determination of the analyte in nutraceutical formulations using dispersive liquid-liquid microextraction(DLLME) coupled with gas chromatography-mass spectrometry method.

General description

Tolylfluanid is a phenylsulfamide fungicide, generally used in fertilizers. It can also be used as an antifouling agent in vessel paints.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ3200
BCCB7968
BCBZ7089
BCBT9907

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Ali Kadar et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1113, 69-76 (2019-03-23)
In this study, an accurate and robust gas chromatography/mass spectrometry method was developed for quantitative analysis of diphenylamine, tolylfluanid, propargite and phosalone in liver fractions. Different injector parameters were optimized by an experimental design technique (central composite design). An optimal
Dispersive liquid-liquid microextraction followed by gas chromatography- mass spectrometry for the determination of pesticide residues in nutraceutical drops.
Szarka A, et al.
Journal of Chromatography A, 1570(1), 126- 134 (2018)
Aurélie Berthet et al.
Toxicology letters, 324, 38-45 (2020-02-18)
Tolylfluanid (TF) is a sensitizing biocide used in antifouling products and wood preservatives. Paint application is associated with skin exposure; however, the importance of this exposure route is uncertain as TF skin permeation rates are lacking in the peer-reviewed scientific
Increase in intracellular Ca2+ level by phenylsulfamide fungicides, tolylfluanid and dichlofluanid, in rat thymic lymphocytes.
Fukunaga E, et al,
Environmental Toxicology and Pharmacology, 40(1), 149- 155 (2015)
S Gielen et al.
Communications in agricultural and applied biological sciences, 71(2 Pt A), 79-82 (2007-03-30)
The use of Euparen Multi (tolylfluanid) for controlling Botrytis cinerea in tomatoes has been decreased the last decade for several reasons. Because of the lack of different fungicides with a good efficacy it is important that growers can use different
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