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Merck
CN

32831

2,4-Diaminoanisole

analytical standard

Synonym(s):

4-Methoxy-m-phenylenediamine

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About This Item

Linear Formula:
CH3OC6H3(NH2)2
CAS Number:
615-05-4
Molecular Weight:
138.17
EC Number:
210-406-1
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329754347
MDL number:
MFCD00007803
Colour Index Number:
76050
Beilstein/REAXYS Number:
2085522

Key Documents

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Product Name

2,4-Diaminoanisole, analytical standard

InChI key

BAHPQISAXRFLCL-UHFFFAOYSA-N

InChI

1S/C7H10N2O/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,8-9H2,1H3

SMILES string

COc1ccc(N)cc1N

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

neat

storage temp.

2-8°C

Quality Level

100

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Application

2,4-Diaminoanisole may be used as an analytical reference standard for the determination of the analyte in:
  • Mainstream waterpipe smoke using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS).
  • Haircolor products by high performance liquid chromatography (HPLC).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

2,4-Diaminoanisole belongs to the class of primary aromatic amines (PAAs). It is categorized as a carcinogenic compound.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B - Muta. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM9283
BCCL8666
BCCK1454
BCCG8870
BCCF7827

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Simultaneous quantitative determination of resorcinol and 1-naphthol in haircolor products by high-performance liquid chromatography.
Wang LH and Kuo YP
Chromatographia, 49(3-4) (1999)
Analysis of primary aromatic amines in the mainstream waterpipe smoke using liquid chromatography-electrospray ionization tandem mass spectrometry.
Schubert J
Journal of Chromatography A, 1218(33), 5628-5637 (2011)
Christopher I Olivares et al.
Journal of hazardous materials, 304, 214-221 (2015-11-10)
Recent studies have begun to assess the environmental fate and toxicity of 2,4-dinitroanisole (DNAN), an insensitive munition compound of interest to defense agencies. Aerobic and anaerobic DNAN biotransformation in soils was evaluated in this study. Under aerobic conditions, there was
Matthew J Berens et al.
Environmental science. Processes & impacts, 21(1), 51-62 (2018-11-30)
The recent development of insensitive munitions, such as 2,4-dinitroanisole (DNAN), as components of military explosives has generated concern for potential subsurface contamination and created a need to fully characterize their transformation processes. Compound specific isotope analysis (CSIA) has proven to
Emese Hadnagy et al.
Environmental science and pollution research international, 25(24), 24403-24416 (2018-06-18)
The manufacturing of insensitive munition 2,4-dinitroanisole (DNAN) generates waste streams that require treatment. DNAN has been treated previously with zero-valent iron (ZVI) and Fe-based bimetals. Use of Mg-based bimetals offers certain advantages including potential higher reactivity and relative insensitivity to

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