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Merck
CN

32831

2,4-Diaminoanisole

analytical standard

Synonym(s):

4-Methoxy-m-phenylenediamine

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About This Item

Linear Formula:
CH3OC6H3(NH2)2
CAS Number:
Molecular Weight:
138.17
EC Number:
210-406-1
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
MDL number:
Colour Index Number:
76050
Beilstein/REAXYS Number:
2085522
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grade

analytical standard

Quality Level

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

neat

storage temp.

2-8°C

SMILES string

COc1ccc(N)cc1N

InChI

1S/C7H10N2O/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,8-9H2,1H3

InChI key

BAHPQISAXRFLCL-UHFFFAOYSA-N

General description

2,4-Diaminoanisole belongs to the class of primary aromatic amines (PAAs). It is categorized as a carcinogenic compound.

Application

2,4-Diaminoanisole may be used as an analytical reference standard for the determination of the analyte in:
  • Mainstream waterpipe smoke using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS).
  • Haircolor products by high performance liquid chromatography (HPLC).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.


signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B - Muta. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges



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Certificates of Analysis (COA)

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Simultaneous quantitative determination of resorcinol and 1-naphthol in haircolor products by high-performance liquid chromatography.
Wang LH and Kuo YP
Chromatographia, 49(3-4) (1999)
Analysis of primary aromatic amines in the mainstream waterpipe smoke using liquid chromatography-electrospray ionization tandem mass spectrometry.
Schubert J
Journal of Chromatography A, 1218(33), 5628-5637 (2011)
Matthew J Berens et al.
Environmental science. Processes & impacts, 21(1), 51-62 (2018-11-30)
The recent development of insensitive munitions, such as 2,4-dinitroanisole (DNAN), as components of military explosives has generated concern for potential subsurface contamination and created a need to fully characterize their transformation processes. Compound specific isotope analysis (CSIA) has proven to



Global Trade Item Number

SKUGTIN
32831-100MG04061835560295