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Merck
CN

32951

TDCPP

PESTANAL®, analytical standard

Synonym(s):

Tris(1,3-dichloro-2-propyl) phosphate, 1,3-Dichloro-2-propanol phosphate, Phosphoric acid tris(1,3-dichloro-2-propyl ester)

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About This Item

Empirical Formula (Hill Notation):
C9H15Cl6O4P
CAS Number:
13674-87-8
Molecular Weight:
430.90
NACRES:
NA.24
PubChem Substance ID:
329754406
UNSPSC Code:
41116107
EC Number:
237-159-2
MDL number:
MFCD00083121

Key Documents

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Product Name

TDCPP, PESTANAL®, analytical standard

InChI key

ASLWPAWFJZFCKF-UHFFFAOYSA-N

InChI

1S/C9H15Cl6O4P/c10-1-7(2-11)17-20(16,18-8(3-12)4-13)19-9(5-14)6-15/h7-9H,1-6H2

SMILES string

ClCC(CCl)OP(=O)(OC(CCl)CCl)OC(CCl)CCl

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

density

1.514 g/mL at 20 °C (lit.)

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
TDCPP may be used as an analytical reference standard for the determination of the analyte in:
  • Eggs by liquid chromatography-tandem quadrupole mass spectrometry (LC-MS/MS).
  • Fish samples by gas chromatography-nitrogen-phosphorus detector (GC-NPD), LC-MS/MS and on-line turbulent flow chromatography (TFC) in conjunction with LC-MS/MS.
  • Environmental samples by GC-MS/MS.
  • Fruits and vegetables by GC-MS/MS and GC coupled with electron capture detection.

General description

TDCPP is classified under the chlorinated trialkyl organophosphate flame retardant (OPFR) group of compounds primarily utilized as additives in commercial products such as plastics, paints, textiles, furniture, etc.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardEnvironment
GHS08,GHS09

signalword

Warning

hcodes

H351,H410

Hazard Classifications

Aquatic Chronic 1 - Carc. 2

Storage Class

10 - Combustible liquids

wgk

WGK 2

flash_point_f

482.0 - 485.6 °F - open cup

flash_point_c

250 - 252 °C - open cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK0213
BCBZ5176

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Determination of non-halogenated, chlorinated and brominated organophosphate flame retardants in herring gull eggs based on liquid chromatography-tandem quadrupole mass spectrometry.
Chen D, et al.
Journal of Chromatography A, 1220(7), 169-174 (2012)
John D Meeker et al.
Environmental health perspectives, 121(5), 580-585 (2013-03-07)
A reduction in the use of polybrominated diphenyl ethers (PBDEs) because of human health concerns may result in an increased use of and human exposure to organophosphate flame retardants (OPFRs). Human exposure and health studies of OPFRs are lacking. We
Simultaneous selective detection of organophosphate and phthalate esters using gas chromatography with positive ion chemical ionization tandem mass spectrometry and its application to indoor air and dust.
Bergh C, et al.
Rapid Communications in Mass Spectrometry, 24(19), 2859-2867 (2010)
Heather M Stapleton et al.
Environmental science & technology, 45(12), 5323-5331 (2011-05-20)
With the phase-out of PentaBDE in 2004, alternative flame retardants are being used in polyurethane foam to meet flammability standards. However, insufficient information is available on the identity of the flame retardants currently in use. Baby products containing polyurethane foam
Simultaneous determination of 16 organophosphorus flame retardants and plasticizers in fish by liquid chromatography-tandem mass spectrometry.
Santin G, et al.
Journal of Chromatography A, 1441(2), 34-43 (2016)
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