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Merck
CN

32952

TCPP, mixture of isomers

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C9H18Cl3O4P
CAS Number:
13674-84-5
Molecular Weight:
327.57
NACRES:
NA.24
UNSPSC Code:
41116107
MDL number:
MFCD00040408
EC Number:
237-158-7
Beilstein/REAXYS Number:
1842347

Key Documents

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Product Name

TCPP, mixture of isomers, PESTANAL®, analytical standard

InChI key

KVMPUXDNESXNOH-UHFFFAOYSA-N

InChI

1S/C9H18Cl3O4P/c1-7(4-10)14-17(13,15-8(2)5-11)16-9(3)6-12/h7-9H,4-6H2,1-3H3

SMILES string

CC(CCl)OP(=O)(OC(C)CCl)OC(C)CCl

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture

format

neat

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

TCPP, mixture of isomers is suitable for use in environmental and food residue analysis. It is a mixture of isomers, composition may vary, typical composition: main isomer tris(1-chloro-2-propyl) phosphate 66%, minor components: bis(1-chloro-2-propyl) (2-chloropropyl) phosphate and (1-chloro-2-propyl) bis(2-chloropropyl) phosphate.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

10 - Combustible liquids

wgk

WGK 2

flash_point_f

365.0 °F - closed cup

flash_point_c

185 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK1920
BCCJ5807
BCBX4369

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Lars Jurzik et al.
International journal of hygiene and environmental health, 213(3), 210-216 (2010-06-18)
There are still conflicting results on the suitability of chemical and microbiological parameters as indicators for the viral contamination of surface waters. In this study, conducted over 20 months, the abundance of human adenovirus, human polyomavirus, enterovirus, group A rotavirus
J Regnery et al.
Journal of environmental monitoring : JEM, 13(2), 347-354 (2010-12-07)
Occurrence and distribution of chlorinated and non-chlorinated organophosphates in 72 groundwater samples from Germany under different recharge/infiltration conditions were investigated. Tris(2-chloro-1-methylethyl) phosphate (TCPP) and tris(2-chloroethyl) phosphate (TCEP) were the most frequently detected organophosphates in groundwater samples. Highest individual organophosphate concentrations
C van Netten et al.
American Industrial Hygiene Association journal, 52(9), 398-400 (1991-09-01)
Air sampling in a government building was necessary in response to reports of a cancer cluster. SKC (Eighty Four, Pa.) charcoal coconut shell-based sorbent tubes (226-01 lot 120) were recommended for this procedure. A recently purchased supply was present at
Julia Regnery et al.
Chemosphere, 78(8), 958-964 (2010-01-16)
To investigate seasonal fluctuations and trends of organophosphate (flame retardants, plasticizers) concentrations in rain and snow, precipitation samples were collected in 2007-2009 period at a densely populated urban sampling site and two sparsely populated rural sampling sites in middle Germany.
Na Li et al.
Ecotoxicology and environmental safety, 183, 109502-109502 (2019-08-09)
The urine levels of organophosphate flame retardants (PFRs) and bisphenol A (BPA) in kindergarten children (n = 31, 4-6 years old, sampling performed in 2016) in Hong Kong were measured. The detection frequency of the target PFRs, tri(2-chloroethyl)phosphate (TCEP), tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
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