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Merck
CN

33398

Bromocyclen

PESTANAL®, analytical standard

Synonym(s):

5- Bromomethyl-1,2,3,4,7,7-hexachloro-2-norbornene

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About This Item

Empirical Formula (Hill Notation):
C8H5BrCl6
CAS Number:
1715-40-8
Molecular Weight:
393.75
NACRES:
NA.24
PubChem Substance ID:
329754524
UNSPSC Code:
41116107
EC Number:
216-996-7
MDL number:
MFCD00151378

Key Documents

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InChI key

DAASOABUJRMZAD-UHFFFAOYSA-N

InChI

1S/C8H5BrCl6/c9-2-3-1-6(12)4(10)5(11)7(3,13)8(6,14)15/h3H,1-2H2

SMILES string

ClC1=C(Cl)C2(Cl)C(CBr)CC1(Cl)C2(Cl)Cl

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, NMR: suitable, gas chromatography (GC): suitable

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

Quality Level

100

Related Categories

General description

Bromocyclen is a cyclodiene insecticide and has been used widely against ectoparasites for treating domestic animals.

Application

Bromocyclen may be used as a reference standard for the determination of bromocyclen in fish tissue samples using solid-phase microextraction coupled to gas chromatography with ECD and ICP–MS detection.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ5906
BCBX0838

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M P Quick
Veterinary and human toxicology, 34(5), 455-457 (1992-10-01)
This report summarizes the case histories and tabulates the analytical results from investigations of 8 incidents of suspected bromocyclen poisoning. Interpretation of the results and withdrawal of ALUGAN from the UK market are discussed.
Bromocyclen contamination of surface water, waste water and fish from northern Germany, and gas chromatographic chiral separation.
Bethan B, et al.
Chemosphere, 34(11), 2271-2280 (1997)
Treatment for bromocyclen poisoning.
M J Priest
The Veterinary record, 127(9), 243-244 (1990-09-01)
Natalia Fidalgo-Used et al.
Talanta, 75(3), 710-716 (2008-07-01)
A method for enantioselective determination of bromocyclen enantiomers in fish tissue has been developed. The enantiomers were resolved by capillary gas chromatography (GC) using a commercial chiral column (CP-Chirasil-Dex CB) and a temperature program from 50 degrees C (held for

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