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Merck
CN

33589

Clothianidin

PESTANAL®, analytical standard

Synonym(s):

(E)-1-(2-Chloro-5-thiazolylmethyl)-3-methyl-2-nitroguanidine

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About This Item

Empirical Formula (Hill Notation):
C6H8ClN5O2S
CAS Number:
210880-92-5
Molecular Weight:
249.68
NACRES:
NA.24
PubChem Substance ID:
329754593
UNSPSC Code:
41116107
MDL number:
MFCD06200753

Key Documents

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InChI

1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)

SMILES string

CN\C(NCc1cnc(Cl)s1)=N/[N+]([O-])=O

InChI key

PGOOBECODWQEAB-UHFFFAOYSA-N

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Related Categories

General description

Clothianidin is a neonicotinoid insecticide with excellent systemic action for a wide variety of insect pests, that acts effectively on nicotinic acetylcholine receptors (nAChR).
Find more information here: Neonicotinoids

Application

Clothianidin may be used as a reference standard for the analysis of the analyte in agricultural samples using dual-labeled time-resolved fluoro-immunoassay (TRFIA), followed by gas chromatography (GC).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

target_organs

Nervous system

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - STOT SE 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ9079
BCCC1790
BCBS3968V

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H Hesketh et al.
Scientific reports, 6, 37655-37655 (2016-12-21)
Concern over reported honeybee (Apis mellifera spp.) losses has highlighted chemical exposure as a risk. Current laboratory oral toxicity tests in A. mellifera spp. use short-term, maximum 96 hour, exposures which may not necessarily account for chronic and cumulative toxicity. Here
Michael DiBartolomeis et al.
PloS one, 14(8), e0220029-e0220029 (2019-08-07)
We present a method for calculating the Acute Insecticide Toxicity Loading (AITL) on US agricultural lands and surrounding areas and an assessment of the changes in AITL from 1992 through 2014. The AITL method accounts for the total mass of
Thiamethoxam is a neonicotinoid precursor converted to clothianidin in insects and plants.
Nauen R, et al.
Pesticide Biochemistry and Physiology, 76(2), 55-69 (2003)
Christof W Schneider et al.
PloS one, 7(1), e30023-e30023 (2012-01-19)
The development of insecticides requires valid risk assessment procedures to avoid causing harm to beneficial insects and especially to pollinators such as the honeybee Apis mellifera. In addition to testing according to current guidelines designed to detect bee mortality, tests
Chemistry of clothianidin and related compounds.
Uneme H.
Journal of Agricultural and Food Chemistry, 59(7), 2932-2937 (2010)
View All Related Papers

Protocols

Neonicotinoids

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Neonicotinoids Ban: Impact on Plant Material

Analysis of banned neonicotinoid insecticides from dandelion blossoms using QuEChERS and LC-MS.

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