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Merck
CN

33730

Dibenzyl dicarbonate

purum, ≥97.0% (HPLC)

Synonym(s):

Dibenzyl pyrocarbonate, Z2O

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About This Item

Linear Formula:
(CO2CH2C6H5)2O
CAS Number:
Molecular Weight:
286.28
PubChem Substance ID:
UNSPSC Code:
12352000
Beilstein/REAXYS Number:
4324796
MDL number:
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grade

purum

assay

≥97.0% (HPLC)

mp

19-22 °C, 29-32 °C (lit.)

density

1.17 g/mL at 25 °C (lit.)

shipped in

dry ice

storage temp.

−20°C

SMILES string

O=C(OCc1ccccc1)OC(=O)OCc2ccccc2

InChI

1S/C16H14O5/c17-15(19-11-13-7-3-1-4-8-13)21-16(18)20-12-14-9-5-2-6-10-14/h1-10H,11-12H2

InChI key

FHRRJZZGSJXPRQ-UHFFFAOYSA-N

Other Notes

Safe reagent for the rapid, clean introduction of the Z-protecting group in amino acids, peptides, etc.; No dipeptides are formed if the pH is controlled


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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E. Wunsch et al.
Synthesis, 958-958 (1986)
G. Sennyey et al.
Tetrahedron Letters, 27, 5375-5375 (1986)