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Imidacloprid-d4

PESTANAL®, analytical standard

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Synonym(s):
Imidazolidin-4,4,5,5-d4
Empirical Formula (Hill Notation):
C9D4H6ClN5O2
CAS Number:
1015855-75-0
Molecular Weight:
259.69
MDL number:
MFCD09037342
PubChem Substance ID:
329754863
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

mass shift

M+4

SMILES string

[2H]C1([2H])N=C(N[N+]([O-])=O)N(Cc2ccc(Cl)nc2)C1([2H])[2H]

InChI

1S/C9H10ClN5O2/c10-8-2-1-7(5-12-8)6-14-4-3-11-9(14)13-15(16)17/h1-2,5H,3-4,6H2,(H,11,13)/i3D2,4D2

InChI key

YWTYJOPNNQFBPC-KHORGVISSA-N

Related Categories

General description

Imidacloprid is a neonicotinoide insecticide primarily applied as a seed dressing and foliar sprays to protect crop in agricultural systems and landscaping.

Find more information here: Neonicotinoids

Application

Imidacloprid-d4 may be used as a surrogate standard in the determination of imidacloprid in honey and pollen samples using solid phase extraction liquid chromatography−tandem mass spectrometry method (SPE-LC-MS/MS).
Imidacloprid-d4 may be used as an internal standard for the determination of the analyte in soil and food matrices by various chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

related product

Product No.
Description
Pricing

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Precautionary Statements

P264 - P270 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Development of a fast and sensitive method for measuring multiple neonicotinoid insecticide residues in soil and the application in parks and residential areas.
Zhou Y, et al.
Analytica Chimica Acta, 1016, 19-28 (2018)
Ian Laycock et al.
PloS one, 8(11), e79872-e79872 (2013-11-14)
Currently, there is concern about declining bee populations and some blame the residues of neonicotinoid pesticides in the nectar and pollen of treated crops. Bumble bees are important wild pollinators that are widely exposed to dietary neonicotinoids by foraging in
Determination of acetamiprid, imidacloprid, and spirotetramat and their relevant metabolites in pistachio using modified QuEChERS combined with liquid chromatography-tandem mass spectrometry.
Faraji M, et al.
Food Chemistry, 240, 634-641 (2018)
Michelle L Hladik et al.
Environmental pollution (Barking, Essex : 1987), 193, 189-196 (2014-07-22)
Neonicotinoid insecticides are of environmental concern, but little is known about their occurrence in surface water. An area of intense corn and soybean production in the Midwestern United States was chosen to study this issue because of the high agricultural
Vijayakumar Bommuraj et al.
Food additives & contaminants. Part B, Surveillance, 13(4), 233-243 (2020-05-15)
Throughout the world, more than six billion people consume milk and milk products yearly. The safety and quality of dairy milk are regularly monitored in most countries worldwide. The Israeli monitoring program of chemical residues in milk has not changed
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Protocols

Neonicotinoids

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Banned and Other Neonicotinoids from Plant Material

On Friday, April 27, 2018, the European Union decided to ban the use of three neonicotinoid insecticides from use on field crops, having deemed them dangerous to bees. This application demonstrates the analysis of these banned compounds and others from dandelion blossoms using QuEChERS and LC-MS.

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