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Merck
CN

36758

Clopyralid

PESTANAL®, analytical standard

Synonym(s):

3,6-Dichloro-pyridine-2-carboxylic acid

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About This Item

Empirical Formula (Hill Notation):
C6H3Cl2NO2
CAS Number:
1702-17-6
Molecular Weight:
192.00
Beilstein:
473755
EC Number:
216-935-4
MDL number:
MFCD00078655
UNSPSC Code:
41116107
PubChem Substance ID:
329755496
NACRES:
NA.24

Key Documents

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grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

OC(=O)c1nc(Cl)ccc1Cl

InChI

1S/C6H3Cl2NO2/c7-3-1-2-4(8)9-5(3)6(10)11/h1-2H,(H,10,11)

InChI key

HUBANNPOLNYSAD-UHFFFAOYSA-N

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General description

Clopyralid is a polar herbicide with a carboxylic acid group, which belongs to the class of pyridine compounds.

Application

Clopyralid may be used as a reference standard for the determination of clopyralid in vegetables and fruits by ultra-performance liquid chromatography(UPLC) coupled with tandem mass spectrometry.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H318

Precautionary Statements

P280 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

>212.0 °F - closed cup

Flash Point(C)

> 100 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCN4142
BCCF3174
BCBZ5263
BCBZ3193

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Persistence studies with the herbicide clopyralid in prairie soils at different temperatures.
A E Smith et al.
Bulletin of environmental contamination and toxicology, 42(5), 670-675 (1989-05-01)
Analysis of the herbicides dicamba, clopyralid and bromacil in asparagus by high-performance liquid chromatography.
D R Lauren et al.
Journal of chromatography, 439(2), 470-475 (1988-05-20)
Daniela V Sojić et al.
Journal of hazardous materials, 168(1), 94-101 (2009-03-07)
The work is concerned with the kinetics, identification of intermediates and reaction pathways of the photocatalytic degradation of the herbicide clopyralid (3,6-dichloropyridine-2-carboxylic acid) in UV illuminated aqueous suspensions of TiO(2) (Degussa P25). In the investigated concentration range (0.5-3.0 mM) the
W C Hayes et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 4(1), 91-97 (1984-02-01)
3,6-Dichloropicolinic acid (clopyralid), a new herbicide, was evaluated for teratogenic potential in Fischer 344 rats and New Zealand White rabbits. Rats were given 0, 15, 75, or 250 mg clopyralid/kg/day by gavage on Days 6-15 of gestation while rabbits were
R Celis et al.
Journal of hazardous materials, 209-210, 67-76 (2012-01-31)
Montmorillonite (SWy-2)-chitosan bionanocomposites (SW-CH) were prepared following different methodologies, characterized, and assayed as adsorbents of the herbicide clopyralid (3,6-dichloropyridine-2-carboxylic acid) in aqueous solution and soil/water suspensions, to assess the potential of the materials to prevent and remediate soil and water
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