36795
Sethoxydim
PESTANAL®, analytical standard
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About This Item
Empirical Formula (Hill Notation):
C17H29NO3S
CAS Number:
Molecular Weight:
327.48
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
277-682-3
Beilstein/REAXYS Number:
8222943
MDL number:
Product Name
Sethoxydim, PESTANAL®, analytical standard
InChI key
CSPPKDPQLUUTND-NBVRZTHBSA-N
InChI
1S/C17H29NO3S/c1-5-8-14(18-21-6-2)17-15(19)10-13(11-16(17)20)9-12(4)22-7-3/h12-13,19H,5-11H2,1-4H3/b18-14+
SMILES string
CCC\C(=N/OCC)C1=C(O)CC(CC(C)SCC)CC1=O
grade
analytical standard
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
storage temp.
−20°C
Quality Level
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Application
The analytical standard can be used to:
- Study the inhibition effect of acetyl-CoA carboxylase in barley chloroplasts using cycloxydim, sethoxydim, and clethodim herbicides
- Study the photochemical changes and oxidative damage in four foxtail millet varieties after exposure to sethoxydim
- Study the resistance mechanism of chloroplastic acetyl-CoA carboxylase from green foxtail (Setaria viridis L. Beauv.) towards cyclohexanedione herbicide sethoxydim
- Study the inhibition mechanism of acetyl-CoA carboxylase by sethoxydim and haloxyfop using a semipurified enzyme preparation extracted from black Mexican sweet maize
- Evaluate the tolerance of 11 grass species used in minimal-to-no-mow turf areas to three postemergence herbicides applied at one- and twofold recommended label rates
- Generate sethoxydim-resistant mutants of Micractinium sp. by UV-C mutagenesis for increased cellular triacylglycerol (TAG) without compromising on growth rate
General description
Sethoxydim is a grass-active herbicide that is very effective for postemergence control of annual and perennial grasses. Sethoxydim belongs to the cyclohexanediones family and is mainly applied to broad-leaved crops, including cotton, oilseed rape, soybeans, sugar beets, fodder beets, sunflowers, spinach, potatoes, tobacco, peanuts, strawberries, alfalfa, flax, and vegetables. The herbicide act by inhibiting plastid acetyl-CoA carboxylase (ACCase) of monocotyledonous species, causing chloroplast bleaching, tissue necrosis, growth reduction, and ultimately death of a plant.
Sethoxydim is not approved for its use in the European Union. Maximum residue levels (MRLs) have been set according to Reg (EC) No 839/2008 for sethoxydim (to be calculated as the sum of sethoxydim and clethodim including degradation products) for various products of plant and animal origin from 0.05 to 1 mg/kg.
Sethoxydim is not approved for its use in the European Union. Maximum residue levels (MRLs) have been set according to Reg (EC) No 839/2008 for sethoxydim (to be calculated as the sum of sethoxydim and clethodim including degradation products) for various products of plant and animal origin from 0.05 to 1 mg/kg.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 2
Storage Class
10 - Combustible liquids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
农药列管产品
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Notes: Inhibition of the Acetyl-CoA Carboxylase of Barley Chloroplasts by Cycloxydim and Sethoxydim
Focke M and Lichtenthaler HK
Zeitschrift fur Naturforschung C, 11-12 null
Shiv Shankhar Kaundun et al.
PloS one, 8(2), e58012-e58012 (2013-03-08)
Acetyl-CoA carboxylase (ACCase) inhibiting herbicides are important products for the post-emergence control of grass weed species in small grain cereal crops. However, the appearance of resistance to ACCase herbicides over time has resulted in limited options for effective weed control
Jinjin Diao et al.
Metabolic engineering, 51, 88-98 (2018-11-06)
Dietary omega-3 long-chain polyunsaturated fatty acids docosahexaenoic acid (DHA, C22:6) can be synthesized in microalgae Crypthecodinium cohnii; however, its productivity is still low. Here, we established a new protocol termed as "chemical modulator based adaptive laboratory evolution" (CM-ALE) to enhance
[Determination of tin compounds in the atmosphere by inversion volt-amperometry].
E M Roĭzenblat et al.
Gigiena i sanitariia, (4)(4), 62-63 (1986-04-01)
Christophe Délye et al.
Planta, 214(3), 421-427 (2002-02-22)
The cDNAs encoding chloroplastic acetyl-CoA carboxylase (ACCase, EC 6.4.1.2) from three lines of Setaria viridis (L. Beauv.) resistant or sensitive to sethoxydim, and from one sethoxydim-sensitive line of Setaria italica (L. Beauv.) were cloned and sequenced. Sequence comparison revealed that
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