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Dimethyl sebacate

analytical standard

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Synonym(s):
Decanedioic acid 1,10-dimethyl ester, Dimethyl decanedioate, NSC 9415, Sebacic acid dimethyl ester
Linear Formula:
CH3OCO(CH2)8COOCH3
CAS Number:
106-79-6
Molecular Weight:
230.30
Beilstein:
1785523
EC Number:
203-431-4
MDL number:
MFCD00008472

grade

analytical standard

Quality Level

100

Assay

≥99.0% (GC)

shelf life

limited shelf life, expiry date on the label

bp

158 °C/10 mmHg (lit.)

mp

29-31 °C (lit.)

density

0.988 g/mL at 25 °C (lit.)

application(s)

environmental

SMILES string

COC(=O)CCCCCCCCC(=O)OC

InChI

1S/C12H22O4/c1-15-11(13)9-7-5-3-4-6-8-10-12(14)16-2/h3-10H2,1-2H3

InChI key

ALOUNLDAKADEEB-UHFFFAOYSA-N

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General description

Dimethyl sebacate is a dicarboxylic acid ester, which is generally prepared by the esterification of sebacic acid. It can be used as a precursor for the preparation of many other sebacates, in polymer syntheses, and finds major application as a plasticizer.

Application

Dimethyl sebacate may be used as an analytical standard for the determination of the analyte in poly(vinyl chloride) gasket seals, oily foodstuffs and nitrocellulose-base propellants by gas chromatography-mass spectrometry (GC-MS) and gas-liquid chromatography (GLC) techniques.

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Z Ezerskis et al.
Analytica chimica acta, 604(1), 29-38 (2007-11-07)
Fourteen poly(vinyl chloride) (PVC) gasket seals and 15 samples of pesto, tomatoes sauces, olive oil and olives in oil were analysed for the additives and plasticisers. The systematic screening of the representative samples revealed that epoxidised soybean oil (ESBO) was
Gas?liquid chromatographic determination of nitrate esters, stabilizers and plasticizers in nitrocellulose-base propellants
Alley BJ and Dykes HWH
Journal of Chromatography A, 71(1), 23-37 (1972)
Esterification of Sebacic Acid in Near-Critical and Supercritical Methanol.
Narayan RC and Madras G
Industrial & Engineering Chemistry Research, 56(10), 2641-2649 (2017)
Experimental determination and theoretical correlation for the solubilities of dicarboxylic acid esters in supercritical carbon dioxide.
Narayan RC, et al.
Journal of Supercritical Fluids, 101, 87-94 (2015)

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