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Merck
CN

42019

Potassium dichromate

reference material for titrimetry, certified by BAM, >99.5%

Synonym(s):

Potassium bichromate

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About This Item

Linear Formula:
K2Cr2O7
CAS Number:
7778-50-9
Molecular Weight:
294.18
NACRES:
NA.24
PubChem Substance ID:
329756173
UNSPSC Code:
41116107
EC Number:
231-906-6
MDL number:
MFCD00011367

Key Documents

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InChI key

KMUONIBRACKNSN-UHFFFAOYSA-N

InChI

1S/2Cr.2K.7O/q;;2*+1;;;;;;2*-1

SMILES string

[K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O

grade

reference material

assay

>99.5%

technique(s)

titration: suitable

mp

398 °C (lit.)

format

neat

Quality Level

100

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General description

Potassium dichromate is an oxidimetric standard produced under stringent conditions and measured with the highest possible precision. Its content determination and homogeneity assessment are performed using volumetric redox titration as the primary analysis method.
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This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Application

It finds its use as a reference material for the standardization of volumetric solutions in redox titrations.

Features and Benefits

  • Available in a neat format in a secure glass bottle to ensure its stability for the entire shelf life until opened.
  • Traceable to NIST SRMs
  • High-quality offering accurate titer determinations
  • Accompanied by a certificate of analysis (CoA)

Analysis Note

Exact concentration, expiry date, traceability and detailed information on certification can be found on the certificate and certification report, included in each package. Content and expiry date on label.

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Cardio-vascular system, Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

易制爆化学品
危险化学品
This item has

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM9145
BCCJ8132
BCCB9372
BCBV2009

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Changes in aquatic toxicity of potassium dichromate as a function of water quality parameters
Kikuchi M, et al.
Chemosphere, 170, 113-117 (2017)
Raman spectroscopic study of oxidation of aniline and N-methylaniline with dichromate
Mazeikiene R, et al.
Journal of Molecular Structure, 1139, 333-337 (2017)
Bour-Jr Wang et al.
Journal of the Formosan Medical Association = Taiwan yi zhi, 110(12), 775-779 (2012-01-18)
Occupational dermatitis among cement workers is a major occupational health concern. The two most important occupational hazards for cement workers are irritant and allergic cement contact dermatitis. The objective of this study was to investigate the severity of occupational cement
Shafaqat Ali et al.
Environmental toxicology and chemistry, 32(10), 2234-2239 (2013-06-19)
A hydroponic experiment was carried out to examine the effect of hydrogen sulfide (H2 S) in alleviating chromium (Cr) stress in barley. A 2-factorial design with 6 replications was selected, including 3 levels of NaHS (0 μM, 100 μM, and
Athanasia G Tekerlekopoulou et al.
Water research, 47(2), 623-636 (2012-11-28)
The kinetics of hexavalent chromium bio-reduction in draw-fill suspended and attached growth reactors was examined using sugar as substrate and indigenous microorganisms from the industrial sludge of the Hellenic Aerospace Industry. Initially, experiments in suspended growth batch reactors for Cr
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