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Merck
CN

45643

Propineb

PESTANAL®, analytical standard

Synonym(s):

Zinc propylenebis(dithiocarbamate)

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About This Item

Linear Formula:
[C5H8N2S4Zn]n
CAS Number:
12071-83-9
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329756857
EC Number:
235-134-0
Beilstein/REAXYS Number:
2360676
MDL number:
MFCD16661267

Key Documents

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Product Name

Propineb, PESTANAL®, analytical standard

InChI key

KKMLIVYBGSAJPM-UHFFFAOYSA-L

InChI

1S/C5H10N2S4.Zn/c1-3(7-5(10)11)2-6-4(8)9;/h3H,2H2,1H3,(H2,6,8,9)(H2,7,10,11);/q;+2/p-2

SMILES string

CC1CNC(=S)S[Zn]SC(=S)N1

grade

analytical standard

description

technical mixture

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

mol wt

Mw 289.78 g/mol

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Propineb may be used as an analytical reference standard for the quantification of the analyte in environmental samples and vegetable samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Propineb belongs to the dithiocarbamates (DTCs) class of fungicides, widely used in agriculture and horticulture. It has an additional advantage of low production cost, broad-spectrum of chemical and biological reactivity.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardEnvironment
GHS08,GHS09

signalword

Warning

Hazard Classifications

Aquatic Chronic 2 - STOT RE 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCM4895
BCCJ6463
BCBT5765
BCBX5669
BCBT9583

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Determination of propylenethiourea, the main metabolite of propineb, in tomato by HILIC-MS
Tolgyesi L, et al.
Chromatographia, 71(1), 75-80 (2010)
Contact allergy due to propineb.
K Nishioka et al.
Contact dermatitis, 43(5), 310-310 (2000-10-04)
Barbara Viviani et al.
Toxicology letters, 182(1-3), 63-68 (2008-09-30)
Neurological complications as well as movement disorders are relevant symptoms in animals and humans chronically exposed to dithiocarbamates. Using rat pheochromocytoma cells differentiated by NGF (PC12), we investigated whether propineb affects acetylcholine (Ach) release and the molecular mechanisms involved. Propineb
I Quinto et al.
Mutation research, 124(3-4), 235-240 (1983-12-01)
Propineb, a dithiocarbamate fungicide, was studied by using the sperm morphology assay in (C57BL6 male X C3H female) F1 mice. At all dose levels, no statistically significant increase in the percentage of sperm abnormalities was observed. Methyl methanesulfonate (MMS) and
Jürgen Pauluhn et al.
Inhalation toxicology, 15(5), 411-434 (2003-04-12)
This article addresses results from repeated 1- and 4-wk inhalation exposure studies in Wistar rats with solid aerosol (dust) atmospheres of propineb, a zinc bisdithiocarbamate homopolymer that is used as an agrochemical fungicide. Groups of 10 rats/sex were exposed nose-only
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